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Three new trifluoromethyl derivatives of [60]fullerene, C60(CF3)12

Nadezhda Borisovna Tamm 1
Nadezhda Borisovna Tamm
, 
Victor Andreevich Brotsman 1
Victor Andreevich Brotsman
, 
1 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
10.1016/j.mencom.2023.10.027
Published 2023-10-18
Communication , Volume 33, Issue 6, 821-822
6
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Tamm N. B., Brotsman V. A., Troyanov S. I. Three new trifluoromethyl derivatives of [60]fullerene, C60(CF3)12 // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 821-822.
GOST all authors (up to 50) Copy
Tamm N. B., Brotsman V. A., Troyanov S. I. Three new trifluoromethyl derivatives of [60]fullerene, C60(CF3)12 // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 821-822.
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TY - JOUR
DO - 10.1016/j.mencom.2023.10.027
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.027
TI - Three new trifluoromethyl derivatives of [60]fullerene, C60(CF3)12
T2 - Mendeleev Communications
AU - Tamm, Nadezhda Borisovna
AU - Brotsman, Victor Andreevich
AU - Troyanov, Sergey Igorevich
PY - 2023
DA - 2023/10/18
PB - Mendeleev Communications
SP - 821-822
IS - 6
VL - 33
ER -
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@article{2023_Tamm,
author = {Nadezhda Borisovna Tamm and Victor Andreevich Brotsman and Sergey Igorevich Troyanov},
title = {Three new trifluoromethyl derivatives of [60]fullerene, C60(CF3)12},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.027},
number = {6},
pages = {821--822},
doi = {10.1016/j.mencom.2023.10.027}
}
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Tamm, Nadezhda Borisovna, et al. “Three new trifluoromethyl derivatives of [60]fullerene, C60(CF3)12.” Mendeleev Communications, vol. 33, no. 6, Oct. 2023, pp. 821-822. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.027.

Keywords

formation energy.
fullerene C60
HPLC separation
structure elucidation
trifluoromethylation

Abstract

Three new C60(CF3)12 isomers have been synthesized by high-temperature trifluoromethylation of [60]fullerene with CF3I, isolated by HPLC, and structurally characterized by single crystal X-ray diffraction.

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