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Adsorption of methane and ethane on HKUST-1 metal-organic framework and mesoporous silica composites

Gregory Sergreevich Deyko 1
Gregory Sergreevich Deyko
, 
Lev Mikhailovich Glukhov 1
Lev Mikhailovich Glukhov
, 
Vera I Isaeva 1
Vera I Isaeva
, 
Vadim Vyacheslavovich Vergun 1
Vadim Vyacheslavovich Vergun
, 
Vladimir Vasilyvich Chernyshev 2, 3
Vladimir Vasilyvich Chernyshev
, 
Gennady Ivanovich Kapustin 1
Gennady Ivanovich Kapustin
, 
Leonid Modestovich Kustov 1, 2, 4
Leonid Modestovich Kustov
2 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
3 A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
4 National University of Science and Technology 'MISIS', Moscow, Russian Federation
10.1016/j.mencom.2023.10.026
Published 2023-10-18
Communication , Volume 33, Issue 6, 817-820
4
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Deyko G. S. et al. Adsorption of methane and ethane on HKUST-1 metal-organic framework and mesoporous silica composites // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 817-820.
GOST all authors (up to 50) Copy
Deyko G. S., Glukhov L. M., Isaeva V. I., Vergun V. V., Chernyshev V. V., Kapustin G. I., Kustov L. M. Adsorption of methane and ethane on HKUST-1 metal-organic framework and mesoporous silica composites // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 817-820.
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TY - JOUR
DO - 10.1016/j.mencom.2023.10.026
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.026
TI - Adsorption of methane and ethane on HKUST-1 metal-organic framework and mesoporous silica composites
T2 - Mendeleev Communications
AU - Deyko, Gregory Sergreevich
AU - Glukhov, Lev Mikhailovich
AU - Isaeva, Vera I
AU - Vergun, Vadim Vyacheslavovich
AU - Chernyshev, Vladimir Vasilyvich
AU - Kapustin, Gennady Ivanovich
AU - Kustov, Leonid Modestovich
PY - 2023
DA - 2023/10/18
PB - Mendeleev Communications
SP - 817-820
IS - 6
VL - 33
ER -
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@article{2023_Deyko,
author = {Gregory Sergreevich Deyko and Lev Mikhailovich Glukhov and Vera I Isaeva and Vadim Vyacheslavovich Vergun and Vladimir Vasilyvich Chernyshev and Gennady Ivanovich Kapustin and Leonid Modestovich Kustov},
title = {Adsorption of methane and ethane on HKUST-1 metal-organic framework and mesoporous silica composites},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.026},
number = {6},
pages = {817--820},
doi = {10.1016/j.mencom.2023.10.026}
}
MLA
Cite this
MLA Copy
Deyko, Gregory Sergreevich, et al. “Adsorption of methane and ethane on HKUST-1 metal-organic framework and mesoporous silica composites.” Mendeleev Communications, vol. 33, no. 6, Oct. 2023, pp. 817-820. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.026.

Keywords

adsorption
ethane.
hybrid materials
mesoporous silica
metal–organic frameworks
methane

Abstract

Composite materials HKUST-1@MCM-41 and HKUST-1@ BPS based on metal-organic framework HKUST-1 [Cu3(btc)2, btc = benzene-1,3,5-tricarboxylate] and silicas, i.e., mesoporous MCM-41 and biporous BPS with a bimodal mesopore size distribution, were prepared by one-step direct growth technique. Methane and ethane adsorption isotherms were measured for the HKUST-1@MCM-41 and HKUST-1@BPS composites in a wide pressure range for the first time. The silica porous structure significantly affects the content and location of HKUST-1 crystallites in these host matrices, and thereby the adsorption selectivities of the composites.

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