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Synthesis of Ni and Mg MOF-derived carbons for potential hydrogen storage applications

Oswaldo Diaz Garza 1
Oswaldo Diaz Garza
, 
Boris Il'dusovich Kharisov 1
Boris Il'dusovich Kharisov
, 
Eduardo M Sanchez Cervantes 1
Eduardo M Sanchez Cervantes
, 
Edith Luevano Hipolito 1
Edith Luevano Hipolito
, 
Oxana V Kharissova 1
Oxana V Kharissova
, 
Leticia M Torres-Martinez 1
Leticia M Torres-Martinez
1 Universidad Autonoma de Nuevo Leon, San Nicolas de los Garza, Nuevo Leon, Mexico
10.1016/j.mencom.2023.10.025
Published 2023-10-18
Communication , Volume 33, Issue 6, 815-816
2
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Diaz Garza O. et al. Synthesis of Ni and Mg MOF-derived carbons for potential hydrogen storage applications // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 815-816.
GOST all authors (up to 50) Copy
Diaz Garza O., Kharisov B. I., Sanchez Cervantes E. M., Luevano Hipolito E., Kharissova O. V., Torres-Martinez L. M. Synthesis of Ni and Mg MOF-derived carbons for potential hydrogen storage applications // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 815-816.
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TY - JOUR
DO - 10.1016/j.mencom.2023.10.025
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.025
TI - Synthesis of Ni and Mg MOF-derived carbons for potential hydrogen storage applications
T2 - Mendeleev Communications
AU - Diaz Garza, Oswaldo
AU - Kharisov, Boris Il'dusovich
AU - Sanchez Cervantes, Eduardo M
AU - Luevano Hipolito, Edith
AU - Kharissova, Oxana V
AU - Torres-Martinez, Leticia M
PY - 2023
DA - 2023/10/18
PB - Mendeleev Communications
SP - 815-816
IS - 6
VL - 33
ER -
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@article{2023_Diaz Garza,
author = {Oswaldo Diaz Garza and Boris Il'dusovich Kharisov and Eduardo M Sanchez Cervantes and Edith Luevano Hipolito and Oxana V Kharissova and Leticia M Torres-Martinez},
title = {Synthesis of Ni and Mg MOF-derived carbons for potential hydrogen storage applications},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.025},
number = {6},
pages = {815--816},
doi = {10.1016/j.mencom.2023.10.025}
}
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Diaz Garza, Oswaldo, et al. “Synthesis of Ni and Mg MOF-derived carbons for potential hydrogen storage applications.” Mendeleev Communications, vol. 33, no. 6, Oct. 2023, pp. 815-816. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.025.

Keywords

Hydrogen storage
metal–organic frameworks
MOF-derived carbon
pyrolysis
spillover effect.
trimesic acid

Abstract

The synthesis of a Ni-trimesic acid (Ni-BTC) metal-organic framework (MOF) under ambient conditions followed by pyrolysis yields a porous MOF-derived carbon (MDC) doped with elemental Ni, appropriate for hydrogen storage applications. The same methods cannot be used for the synthesis of Mg-BTC MOF and its MDC as the reactivity of Mg towards BTC is not sufficient to prevent competing reactions, and Mg is oxidized to MgO during pyrolysis, preventing hydrogen storage via the formation of MgH2.

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