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1,4-Difluoro-2,5-dimethyl-3,6-bis(diphenylphosphoryl)benzene: Regioselective synthesis and coordination with Mn2+ cation

Oleg Ivanovich Artyushin 1
Oleg Ivanovich Artyushin
, 
Anna Grigoryevna Matveeva 1
Anna Grigoryevna Matveeva
, 
Anna Vladimirovna Vologzhanina 1
Anna Vladimirovna Vologzhanina
, 
Pavel Vladimirovich Dorovatovskii 2
Pavel Vladimirovich Dorovatovskii
, 
1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
2 National Research Centre 'Kurchatov Institute', Moscow, Russian Federation
10.1016/j.mencom.2023.10.009
Published 2023-10-18
Communication , Volume 33, Issue 6, 767-768
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Artyushin O. I. et al. 1,4-Difluoro-2,5-dimethyl-3,6-bis(diphenylphosphoryl)benzene: Regioselective synthesis and coordination with Mn2+ cation // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 767-768.
GOST all authors (up to 50) Copy
Artyushin O. I., Matveeva A. G., Vologzhanina A. V., Dorovatovskii P. V., Brel V. K. 1,4-Difluoro-2,5-dimethyl-3,6-bis(diphenylphosphoryl)benzene: Regioselective synthesis and coordination with Mn2+ cation // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 767-768.
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TY - JOUR
DO - 10.1016/j.mencom.2023.10.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.009
TI - 1,4-Difluoro-2,5-dimethyl-3,6-bis(diphenylphosphoryl)benzene: Regioselective synthesis and coordination with Mn2+ cation
T2 - Mendeleev Communications
AU - Artyushin, Oleg Ivanovich
AU - Matveeva, Anna Grigoryevna
AU - Vologzhanina, Anna Vladimirovna
AU - Dorovatovskii, Pavel Vladimirovich
AU - Brel, Valery Kuzmich
PY - 2023
DA - 2023/10/18
PB - Mendeleev Communications
SP - 767-768
IS - 6
VL - 33
ER -
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@article{2023_Artyushin,
author = {Oleg Ivanovich Artyushin and Anna Grigoryevna Matveeva and Anna Vladimirovna Vologzhanina and Pavel Vladimirovich Dorovatovskii and Valery Kuzmich Brel},
title = {1,4-Difluoro-2,5-dimethyl-3,6-bis(diphenylphosphoryl)benzene: Regioselective synthesis and coordination with Mn2+ cation},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.009},
number = {6},
pages = {767--768},
doi = {10.1016/j.mencom.2023.10.009}
}
MLA
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Artyushin, Oleg Ivanovich, et al. “1,4-Difluoro-2,5-dimethyl-3,6-bis(diphenylphosphoryl)benzene: Regioselective synthesis and coordination with Mn2+ cation.” Mendeleev Communications, vol. 33, no. 6, Oct. 2023, pp. 767-768. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.009.

Keywords

1
4-difluoro-2
5-dimethyl-3
6-bis(diphenylphosphoryl)benzene
manganese(II) complexes
NMR spectroscopy.
organofluorine compounds
organophosphorus compounds
phosphine oxides
phosphines
X-ray diffraction analysis

Abstract

Regioselective synthesis of 1,4-difluoro-2,5-dimethyl-3,6-bis-(diphenylphosphoryl)benzene from 1,2,4,5-tetraflouro-3,6-dimethylbenzene and preparation of its coordination polymer with Mn2+ have been developed. The structures of the ligand and the complex have been determined by X-ray diffraction.

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