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Organic derivatives of group 14 elements: General aspects of synthesis, modern trends, and application prospects

Elena Nikolaevna Nikolaevskaya 1
Elena Nikolaevna Nikolaevskaya
Mikhail Aleksandrovich Syroeshkin 1
Mikhail Aleksandrovich Syroeshkin
Mikhail Petrovich Egorov 1
Mikhail Petrovich Egorov
Published 2023-10-18
Focus articleVolume 33, Issue 6, 733-745
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Nikolaevskaya E. N., Syroeshkin M. A., Egorov M. P. Organic derivatives of group 14 elements: General aspects of synthesis, modern trends, and application prospects // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 733-745.
GOST all authors (up to 50) Copy
Nikolaevskaya E. N., Syroeshkin M. A., Egorov M. P. Organic derivatives of group 14 elements: General aspects of synthesis, modern trends, and application prospects // Mendeleev Communications. 2023. Vol. 33. No. 6. pp. 733-745.
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TY - JOUR
DO - 10.1016/j.mencom.2023.10.001
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.001
TI - Organic derivatives of group 14 elements: General aspects of synthesis, modern trends, and application prospects
T2 - Mendeleev Communications
AU - Nikolaevskaya, Elena Nikolaevna
AU - Syroeshkin, Mikhail Aleksandrovich
AU - Egorov, Mikhail Petrovich
PY - 2023
DA - 2023/10/18
PB - Mendeleev Communications
SP - 733-745
IS - 6
VL - 33
ER -
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@article{2023_Nikolaevskaya,
author = {Elena Nikolaevna Nikolaevskaya and Mikhail Aleksandrovich Syroeshkin and Mikhail Petrovich Egorov},
title = {Organic derivatives of group 14 elements: General aspects of synthesis, modern trends, and application prospects},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.001},
number = {6},
pages = {733--745},
doi = {10.1016/j.mencom.2023.10.001}
}
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Nikolaevskaya, Elena Nikolaevna, et al. “Organic derivatives of group 14 elements: General aspects of synthesis, modern trends, and application prospects.” Mendeleev Communications, vol. 33, no. 6, Oct. 2023, pp. 733-745. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.10.001.
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Keywords

application prospects
complexes
germanium
Lewis acids.
organic derivatives
silicon
tin

Abstract

A general aspect of synthesis, modern trends and application prospects of organic derivatives of group 14 elements are briefly overviewed. This survey concerns actual research areas with pronounceable scientific sound such as Lewis acidity of catecholate silicon and germanium complexes, their ability to give free radicals and low valence 14 group derivatives. The main recent trends (published mainly within 2017-2022) in the chemistry of group 14 derivatives which are of paramount importance for the development of new catalytic systems, fluorescent marks, activation of small molecules and frustrated Lewis pair (FLP) chemistry are summarized.

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Levernier E., Jaouadi K., Zhang H., Corcé V., Bernard A., Gontard G., Troufflard C., Grimaud L., Derat E., Ollivier C., Fensterbank L.
Chemistry - A European Journal, 2021
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Hypervalent Compounds of Organic Germanium, Tin and Lead Derivatives
Baukov Y.I., Tandura S.N.
Chemistry of Functional Groups, 2002
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HETEROCYCLIC HEAVY ANALOGUES OF CARBENES: STRUCTURE AND CHEMICAL PROPERTIES. REVIEW
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Hirmer S.V., Tschernuth F.S., Hanusch F., Baierl R., Muhr M., Inoue S.
Mendeleev Communications, 2022
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Nikolin A.A., Korlyukov A.A., Kramarova E.P., Romanenko A.R., Arkhipov D.E., Tarasenko D.V., Bylikin S.Y., Baukov Y.I., Negrebetsky V.V.
Mendeleev Communications, 2022
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Structure and stability of MCl4 carbene complexes (M = Si, Ge, Sn): Experiment and theory
Davydova E.I., Balázs G., Bodensteiner M., Scheer M., Timoshkin A.Y.
Journal of Organometallic Chemistry, 2023
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Sn and Ge Complexes with Redox-Active Ligands as Efficient Interfacial Membrane-like Buffer Layers for p-i-n Perovskite Solar Cells
Akbulatov A.F., Akyeva A.Y., Shangin P.G., Emelianov N.A., Krylova I.V., Markova M.O., Labutskaya L.D., Mumyatov A.V., Tuzharov E.I., Bunin D.A., Frolova L.A., Egorov M.P., Syroeshkin M.A., Troshin P.A.
Membranes, 2023
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Germanium Complexes with ONO Tridentate Ligands: O-H Bond Activation Control According to DFT Calculations
Zaitsev K.V., Trubachev A.D., Poleshchuk O.K.
International Journal of Molecular Sciences, 2023