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Column chromatography separation of lanthanide(III) bisphthalocyaninate and phthalocyanine ligand

Anna Alexandrovna Botnar 1
Anna Alexandrovna Botnar
, 
Tatyana Vyacheslavovna Tikhomirova 1
Tatyana Vyacheslavovna Tikhomirova
, 
1 Ivanovo State University of Chemistry and Technology, Ivanovo, Russian Federation
10.1016/j.mencom.2023.09.044
Published 2023-09-01
Communication , Volume 33, Issue 5, 729-731
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Botnar A. A., Tikhomirova T. V., Vashurin A. S. Column chromatography separation of lanthanide(III) bisphthalocyaninate and phthalocyanine ligand // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 729-731.
GOST all authors (up to 50) Copy
Botnar A. A., Tikhomirova T. V., Vashurin A. S. Column chromatography separation of lanthanide(III) bisphthalocyaninate and phthalocyanine ligand // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 729-731.
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TY - JOUR
DO - 10.1016/j.mencom.2023.09.044
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.044
TI - Column chromatography separation of lanthanide(III) bisphthalocyaninate and phthalocyanine ligand
T2 - Mendeleev Communications
AU - Botnar, Anna Alexandrovna
AU - Tikhomirova, Tatyana Vyacheslavovna
AU - Vashurin, Artur Sergeevich
PY - 2023
DA - 2023/09/01
PB - Mendeleev Communications
SP - 729-731
IS - 5
VL - 33
ER -
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@article{2023_Botnar,
author = {Anna Alexandrovna Botnar and Tatyana Vyacheslavovna Tikhomirova and Artur Sergeevich Vashurin},
title = {Column chromatography separation of lanthanide(III) bisphthalocyaninate and phthalocyanine ligand},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.044},
number = {5},
pages = {729--731},
doi = {10.1016/j.mencom.2023.09.044}
}
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Botnar, Anna Alexandrovna, et al. “Column chromatography separation of lanthanide(III) bisphthalocyaninate and phthalocyanine ligand.” Mendeleev Communications, vol. 33, no. 5, Sep. 2023, pp. 729-731. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.044.

Keywords

chromatography.
double-decker complex
lanthanide
ligand
phthalocyanine

Abstract

During the synthesis of double-decker f-metal phthalocyanine complexes Ln(Pc)2 free phthalocyanine ligands can be also formed, however, routine column chromatography is not effective for their separation. The preliminary reduction of the complexes with hydrazine hydrate affords the low mobile forms, which can be re-oxidized in the chromatography columns after the free ligand is eluted.

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