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Semicarbazones of alkyl 3-nitropyruvates: Synthesis and structural features

Vasilii Vasil'evich Pelipko 1
Vasilii Vasil'evich Pelipko
, 
Ilya Aleksandrovich Pilipenko 1
Ilya Aleksandrovich Pilipenko
, 
Kirill Aleksandrovich Gomonov 1
Kirill Aleksandrovich Gomonov
, 
Ruslan Izmailovich Baichurin 1
Ruslan Izmailovich Baichurin
, 
Konstantin Alexandrovich Lyssenko 2
Konstantin Alexandrovich Lyssenko
, 
Sergey Valentinovich Makarenko 1
Sergey Valentinovich Makarenko
1 Herzen State Pedagogical University of Russia, St. Petersburg, Russian Federation
2 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
10.1016/j.mencom.2023.09.042
Published 2023-09-01
Communication , Volume 33, Issue 5, 723-725
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Pelipko V. V. et al. Semicarbazones of alkyl 3-nitropyruvates: Synthesis and structural features // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 723-725.
GOST all authors (up to 50) Copy
Pelipko V. V., Pilipenko I. A., Gomonov K. A., Baichurin R. I., Lyssenko K. A., Makarenko S. V. Semicarbazones of alkyl 3-nitropyruvates: Synthesis and structural features // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 723-725.
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TY - JOUR
DO - 10.1016/j.mencom.2023.09.042
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.042
TI - Semicarbazones of alkyl 3-nitropyruvates: Synthesis and structural features
T2 - Mendeleev Communications
AU - Pelipko, Vasilii Vasil'evich
AU - Pilipenko, Ilya Aleksandrovich
AU - Gomonov, Kirill Aleksandrovich
AU - Baichurin, Ruslan Izmailovich
AU - Lyssenko, Konstantin Alexandrovich
AU - Makarenko, Sergey Valentinovich
PY - 2023
DA - 2023/09/01
PB - Mendeleev Communications
SP - 723-725
IS - 5
VL - 33
ER -
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@article{2023_Pelipko,
author = {Vasilii Vasil'evich Pelipko and Ilya Aleksandrovich Pilipenko and Kirill Aleksandrovich Gomonov and Ruslan Izmailovich Baichurin and Konstantin Alexandrovich Lyssenko and Sergey Valentinovich Makarenko},
title = {Semicarbazones of alkyl 3-nitropyruvates: Synthesis and structural features},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.042},
number = {5},
pages = {723--725},
doi = {10.1016/j.mencom.2023.09.042}
}
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Pelipko, Vasilii Vasil'evich, et al. “Semicarbazones of alkyl 3-nitropyruvates: Synthesis and structural features.” Mendeleev Communications, vol. 33, no. 5, Sep. 2023, pp. 723-725. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.042.

Keywords

aza-Michael adduct
elimination
nitroacrylates
nitropyruvates.
nucleophilic addition
semicarbazides
semicarbazones

Abstract

Semicarbazones of alkyl 3-nitropyruvates were obtained by the reaction between alkyl 3-bromo-3-nitroacrylates and semicarbazides. The products were formed as E/Z isomer mixtures from which some representatives of the individual isomers were isolated. The possibility of their isomerization was shown.

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