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Green coupling of 3,5-diamino-1H-1,2,4-triazole into the azo compound

Mingzhen Xie 1
Mingzhen Xie
, 
Jiaxu Gong 1
Jiaxu Gong
, 
Jie Zhou 1
Jie Zhou
, 
Jiaheng Wang 1
Jiaheng Wang
, 
Yulong Cao 1
Yulong Cao
, 
Tianlong Zhou 1, 2
Tianlong Zhou
, 
Yatang Dai 1, 3
Yatang Dai
1 Department of Chemistry, Southwest University of Science and Technology, Mianyang, P.R. China
2 Xi'an Modern Chemistry Research Institute, Xi'an, P.R. China
3 School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang, P.R. China
10.1016/j.mencom.2023.09.040
Published 2023-09-01
Communication , Volume 33, Issue 5, 717-720
4
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Xie M. et al. Green coupling of 3,5-diamino-1H-1,2,4-triazole into the azo compound // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 717-720.
GOST all authors (up to 50) Copy
Xie M., Gong J., Zhou J., Wang J., Cao Y., Zhou T., Dai Y. Green coupling of 3,5-diamino-1H-1,2,4-triazole into the azo compound // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 717-720.
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TY - JOUR
DO - 10.1016/j.mencom.2023.09.040
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.040
TI - Green coupling of 3,5-diamino-1H-1,2,4-triazole into the azo compound
T2 - Mendeleev Communications
AU - Xie, Mingzhen
AU - Gong, Jiaxu
AU - Zhou, Jie
AU - Wang, Jiaheng
AU - Cao, Yulong
AU - Zhou, Tianlong
AU - Dai, Yatang
PY - 2023
DA - 2023/09/01
PB - Mendeleev Communications
SP - 717-720
IS - 5
VL - 33
ER -
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@article{2023_Xie,
author = {Mingzhen Xie and Jiaxu Gong and Jie Zhou and Jiaheng Wang and Yulong Cao and Tianlong Zhou and Yatang Dai},
title = {Green coupling of 3,5-diamino-1H-1,2,4-triazole into the azo compound},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.040},
number = {5},
pages = {717--720},
doi = {10.1016/j.mencom.2023.09.040}
}
MLA
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MLA Copy
Xie, Mingzhen, et al. “Green coupling of 3,5-diamino-1H-1,2,4-triazole into the azo compound.” Mendeleev Communications, vol. 33, no. 5, Sep. 2023, pp. 717-720. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.040.

Keywords

active site
azo compounds
clean and efficient
conjugation reaction
electrochemical synthesis
triazoles
voltage control.

Abstract

The nitrogen-nitrogen double bond between two molecules of 3,5-diamino-1H-1,2,4-triazole is successfully constructed using a one-step electrochemical coupling method. The oxidation occurs selectively when the electrochemical parameters are properly adjusted to provide a yield of 45.77%. Subsequently, the oxidative coupling of this substrate with electrochemically generated hydroxy nickel oxide or sodium hypochlorite is verified.

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