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New electron-deficient 2,1,3-benzothiadiazole-cored donor-acceptor compounds: Synthesis, photophysical and electroluminescent properties

, 
Dmitry Alexandrovich Loginov 1, 2
Dmitry Alexandrovich Loginov
, 
Dmitry Alexandrovich Lypenko 3
Dmitry Alexandrovich Lypenko
, 
Artem Vladimirovich Dmitriev 3
Artem Vladimirovich Dmitriev
, 
Sergey Dmitrievich Tokarev 1
Sergey Dmitrievich Tokarev
, 
Alexey Evgenievich Aleksandrov 3
Alexey Evgenievich Aleksandrov
, 
Alexey Raisovich Tameev 3
Alexey Raisovich Tameev
,  , 
Sergey Nikolaevich Osipov 1
Sergey Nikolaevich Osipov
1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
2 G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation
3 A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
10.1016/j.mencom.2023.09.035
Published 2023-09-01
Communication , Volume 33, Issue 5, 701-704
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Gribanov P. S. et al. New electron-deficient 2,1,3-benzothiadiazole-cored donor-acceptor compounds: Synthesis, photophysical and electroluminescent properties // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 701-704.
GOST all authors (up to 50) Copy
Gribanov P. S., Loginov D. A., Lypenko D. A., Dmitriev A. V., Tokarev S. D., Aleksandrov A. E., Tameev A. R., Chernyadyev A. Y., Osipov S. N. New electron-deficient 2,1,3-benzothiadiazole-cored donor-acceptor compounds: Synthesis, photophysical and electroluminescent properties // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 701-704.
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TY - JOUR
DO - 10.1016/j.mencom.2023.09.035
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.035
TI - New electron-deficient 2,1,3-benzothiadiazole-cored donor-acceptor compounds: Synthesis, photophysical and electroluminescent properties
T2 - Mendeleev Communications
AU - Gribanov, Pavel Sergeevich
AU - Loginov, Dmitry Alexandrovich
AU - Lypenko, Dmitry Alexandrovich
AU - Dmitriev, Artem Vladimirovich
AU - Tokarev, Sergey Dmitrievich
AU - Aleksandrov, Alexey Evgenievich
AU - Tameev, Alexey Raisovich
AU - Chernyadyev, Andrey Yuryevich
AU - Osipov, Sergey Nikolaevich
PY - 2023
DA - 2023/09/01
PB - Mendeleev Communications
SP - 701-704
IS - 5
VL - 33
ER -
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@article{2023_Gribanov,
author = {Pavel Sergeevich Gribanov and Dmitry Alexandrovich Loginov and Dmitry Alexandrovich Lypenko and Artem Vladimirovich Dmitriev and Sergey Dmitrievich Tokarev and Alexey Evgenievich Aleksandrov and Alexey Raisovich Tameev and Andrey Yuryevich Chernyadyev and Sergey Nikolaevich Osipov},
title = {New electron-deficient 2,1,3-benzothiadiazole-cored donor-acceptor compounds: Synthesis, photophysical and electroluminescent properties},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.035},
number = {5},
pages = {701--704},
doi = {10.1016/j.mencom.2023.09.035}
}
MLA
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MLA Copy
Gribanov, Pavel Sergeevich, et al. “New electron-deficient 2,1,3-benzothiadiazole-cored donor-acceptor compounds: Synthesis, photophysical and electroluminescent properties.” Mendeleev Communications, vol. 33, no. 5, Sep. 2023, pp. 701-704. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.035.

Keywords

benzothiadiazole
cross-coupling
luminescence
luminophore
OLED.

Abstract

Three new 2,1,3-benzothiadiazole-containing luminophores with different electron deficiency of acceptor block have been prepared via the Pd-catalyzed Suzuki cross-coupling and nucleophilic fluorine substitution with cyano group. Photophysical and electroluminescent properties of the compounds obtained were investigated to estimate their potential for optoelectronic applications. The introduction of two fluorine atoms in the benzothiadiazole moiety leads to the hypsochromic shift of the electroluminescent emission, whereas the incorporation of two cyano groups shifts it into the long-wave region. All synthesized compounds were used as emissive layers in OLED devises.

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