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Magnetically recyclable Cu-BTC@Fe3O4-catalyzed synthesis of cyano functionalized chroman-4-ones

Yongsheng Zhou 1
Yongsheng Zhou
, 
Liang Wang 2
Liang Wang
1 School of Petrochemical Engineering, Changzhou University, Changzhou, China
2 School of Chemical and Pharmaceutical Engineering, Changzhou Vocational Institute of Engineering, Changzhou, P.R. China
10.1016/j.mencom.2023.09.034
Published 2023-09-01
Communication , Volume 33, Issue 5, 699-700
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Zhou Y., Wang L. Magnetically recyclable Cu-BTC@Fe3O4-catalyzed synthesis of cyano functionalized chroman-4-ones // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 699-700.
GOST all authors (up to 50) Copy
Zhou Y., Wang L. Magnetically recyclable Cu-BTC@Fe3O4-catalyzed synthesis of cyano functionalized chroman-4-ones // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 699-700.
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TY - JOUR
DO - 10.1016/j.mencom.2023.09.034
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.034
TI - Magnetically recyclable Cu-BTC@Fe3O4-catalyzed synthesis of cyano functionalized chroman-4-ones
T2 - Mendeleev Communications
AU - Zhou, Yongsheng
AU - Wang, Liang
PY - 2023
DA - 2023/09/01
PB - Mendeleev Communications
SP - 699-700
IS - 5
VL - 33
ER -
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@article{2023_Zhou,
author = {Yongsheng Zhou and Liang Wang},
title = {Magnetically recyclable Cu-BTC@Fe3O4-catalyzed synthesis of cyano functionalized chroman-4-ones},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.034},
number = {5},
pages = {699--700},
doi = {10.1016/j.mencom.2023.09.034}
}
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Zhou, Yongsheng, and Liang Wang. “Magnetically recyclable Cu-BTC@Fe3O4-catalyzed synthesis of cyano functionalized chroman-4-ones.” Mendeleev Communications, vol. 33, no. 5, Sep. 2023, pp. 699-700. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.034.

Keywords

chroman-4-ones
cyanation
magnetic catalyst
metal–organic frameworks
peroxides.
radical cascade reaction

Abstract

An intramolecular radical cascade acyl-cyanation of o-(allyloxy)benzaldehydes with Me3SiCN using magnetically recyclable Cu-BTC@Fe3O4 catalyst (BTC = 1,3,5-benzenetri- carboxylate) and peroxides as the stoichiometric oxidants affords 3-cyanomethyl-functionalized chroman-4-ones in moderate to good yields. The catalyst can be readily recovered with an external permanent magnet, with slight decrease in its activity after successive five runs.

References

.
Magnetically retrievable catalysts for organic synthesis
Baig R.B., Varma R.S.
Chemical Communications, 2013
.
Isolation and Characterization of New Anti-HIV and Cytotoxic Leads from Plants, Marine, and Microbial Organisms
McKee T.C., Bokesch H.R., McCormick J.L., Rashid M.A., Spielvogel D., Gustafson K.R., Alavanja M.M., Cardellina J.H., Boyd M.R.
Journal of Natural Products, 1997
.
N-Heterocyclic Carbene-Catalyzed Hydroacylation of Unactivated Double Bonds
Hirano K., Biju A.T., Piel I., Glorius F.
Journal of the American Chemical Society, 2009
.
Synthesis of 2-Alkyl-Substituted Chromone Derivatives Using Microwave Irradiation
Fridén-Saxin M., Pemberton N., da Silva Andersson K., Dyrager C., Friberg A., Grøtli M., Luthman K.
Journal of Organic Chemistry, 2009
.
Chroman-4-one- and Chromone-Based Sirtuin 2 Inhibitors with Antiproliferative Properties in Cancer Cells
Seifert T., Malo M., Kokkola T., Engen K., Fridén-Saxin M., Wallén E.A., Lahtela-Kakkonen M., Jarho E.M., Luthman K.
Journal of Medicinal Chemistry, 2014
.
Magnetically recyclable Cu-BTC@Fe3O4-catalyzed chlorosulfonylation of vinylarenes
Zhang X., Wang L., Zhu Q.
Phosphorus, Sulfur and Silicon and the Related Elements, 2022
.
Magnetically recyclable Cu-BTC@Fe3O4 composite-catalyzed C(aryl)–S–P bond formation using aniline, P(O)H compounds and sulfur powder
Wang L., Yang S., Chen L., Yuan S., Chen Q., He M., Zhang Z.
Catalysis Science and Technology, 2017
.
Silver-catalyzed decarboxylative cascade radical cyclization of tert-carboxylic acids and o-(allyloxy)arylaldehydes towards chroman-4-one derivatives
Hu H., Chen X., Sun K., Wang J., Liu Y., Liu H., Yu B., Sun Y., Qu L., Zhao Y.
Organic Chemistry Frontiers, 2018
.
Transition-metal-free synthesis of CMe2CF3-containing chroman-4-ones via decarboxylative trifluoroalkylation
Liu M., Liu W., Wu H., Zhou Y., Ding Q., Peng Y.
Organic Chemistry Frontiers, 2020