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Hexacoordinate germanium compounds with BIS-TRIS and amino acid ligands

Igor Sergeyevich Ignatyev 1
Igor Sergeyevich Ignatyev
, 
Yulia Andreevna Kondratenko 1
Yulia Andreevna Kondratenko
, 
Denis Vital'evich Lezov 1
Denis Vital'evich Lezov
, 
Valery Leonidovich Ugolkov 1
Valery Leonidovich Ugolkov
, 
Tat'yana Aleksandrovna Kochina 1
Tat'yana Aleksandrovna Kochina
1 I.V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, St. Petersburg, Russian Federation
10.1016/j.mencom.2023.09.003
Published 2023-09-01
Communication , Volume 33, Issue 5, 601-604
3
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Ignatyev I. S. et al. Hexacoordinate germanium compounds with BIS-TRIS and amino acid ligands // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 601-604.
GOST all authors (up to 50) Copy
Ignatyev I. S., Kondratenko Y. A., Lezov D. V., Ugolkov V. L., Kochina T. A. Hexacoordinate germanium compounds with BIS-TRIS and amino acid ligands // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 601-604.
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TY - JOUR
DO - 10.1016/j.mencom.2023.09.003
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.003
TI - Hexacoordinate germanium compounds with BIS-TRIS and amino acid ligands
T2 - Mendeleev Communications
AU - Ignatyev, Igor Sergeyevich
AU - Kondratenko, Yulia Andreevna
AU - Lezov, Denis Vital'evich
AU - Ugolkov, Valery Leonidovich
AU - Kochina, Tat'yana Aleksandrovna
PY - 2023
DA - 2023/09/01
PB - Mendeleev Communications
SP - 601-604
IS - 5
VL - 33
ER -
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@article{2023_Ignatyev,
author = {Igor Sergeyevich Ignatyev and Yulia Andreevna Kondratenko and Denis Vital'evich Lezov and Valery Leonidovich Ugolkov and Tat'yana Aleksandrovna Kochina},
title = {Hexacoordinate germanium compounds with BIS-TRIS and amino acid ligands},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.003},
number = {5},
pages = {601--604},
doi = {10.1016/j.mencom.2023.09.003}
}
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Ignatyev, Igor Sergeyevich, et al. “Hexacoordinate germanium compounds with BIS-TRIS and amino acid ligands.” Mendeleev Communications, vol. 33, no. 5, Sep. 2023, pp. 601-604. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.09.003.

Keywords

1-germatranol hydrate
amino acids
BIS-TRIS
germatranes
M06-L DFT method.
triethanolamine

Abstract

New germanium-containing compounds of the atrane family have been synthesized by reacting germanium glycinate, L-α-alaninate and L-valinate with [bis(2-hydroxyethyl)-amino][tris(hydroxymethyl)]methane (BIS-TRIS) and explored by FT-IR, NMR spectroscopy, thermal and elemental analysis. The fully local meta-GGA correlation functional (M06-L) was applied to investigate their equilibrium geometries. The derivatives of BIS-TRIS and triethanolamine have been investigated by computational screening via ADMET and PASS software.

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