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Synthesis and thermal behavior of RAFT-based copolymers of acrylonitrile and 1-vinylimidazole

Natalia Ivanovna Osipova 1
Natalia Ivanovna Osipova
, 
Anna V Plutalova 1
Anna V Plutalova
,  , 
Nikolay Ivanovich Prokopov 2
Nikolay Ivanovich Prokopov
, 
1 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
2 M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation
10.1016/j.mencom.2023.06.041
Published 2023-06-13
Communication , Volume 33, Issue 4, 568-571
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Osipova N. I. et al. Synthesis and thermal behavior of RAFT-based copolymers of acrylonitrile and 1-vinylimidazole // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 568-571.
GOST all authors (up to 50) Copy
Osipova N. I., Plutalova A. V., Toms R. V., Prokopov N. I., Chernikova E. V. Synthesis and thermal behavior of RAFT-based copolymers of acrylonitrile and 1-vinylimidazole // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 568-571.
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TY - JOUR
DO - 10.1016/j.mencom.2023.06.041
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.041
TI - Synthesis and thermal behavior of RAFT-based copolymers of acrylonitrile and 1-vinylimidazole
T2 - Mendeleev Communications
AU - Osipova, Natalia Ivanovna
AU - Plutalova, Anna V
AU - Toms, Roman Vladimirovich
AU - Prokopov, Nikolay Ivanovich
AU - Chernikova, Elena Vyacheslavna
PY - 2023
DA - 2023/06/13
PB - Mendeleev Communications
SP - 568-571
IS - 4
VL - 33
ER -
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@article{2023_Osipova,
author = {Natalia Ivanovna Osipova and Anna V Plutalova and Roman Vladimirovich Toms and Nikolay Ivanovich Prokopov and Elena Vyacheslavna Chernikova},
title = {Synthesis and thermal behavior of RAFT-based copolymers of acrylonitrile and 1-vinylimidazole},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.041},
number = {4},
pages = {568--571},
doi = {10.1016/j.mencom.2023.06.041}
}
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Osipova, Natalia Ivanovna, et al. “Synthesis and thermal behavior of RAFT-based copolymers of acrylonitrile and 1-vinylimidazole.” Mendeleev Communications, vol. 33, no. 4, Jun. 2023, pp. 568-571. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.041.

Keywords

1-vinylimidazole
acrylonitrile copolymers
Cyclization
melt spinning.
reversible addition–fragmentation chain transfer polymerization
thermo-oxidative stabilization

Abstract

The copolymers of acrylonitrile and 1-vinylimidazole with a narrow molecular weight distribution (MWD) were synthesized for the first time by the reversible addition-fragmentation chain transfer (RAFT) polymerization in a DMSO solution in the presence of acetic acid. Their thermal behavior difference upon heating in argon and in air along with ability to melt make them promising precursors for carbon fiber production.

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