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Synthesis and X-ray diffraction analysis of coenzyme Q derivatives obtained from natural polyalkoxyallylbenzenes

Dmitry Vadimovich Tsyganov 1
Dmitry Vadimovich Tsyganov
,  , 
Olga Igorevna Adaeva 1
Olga Igorevna Adaeva
, 
Leonid Dmitrievich Konyushkin 1
Leonid Dmitrievich Konyushkin
,  , 
Victor Nikolaevich Khrustalev 1, 2
Victor Nikolaevich Khrustalev
, 
Victor Vladimirovich Semenov 1
Victor Vladimirovich Semenov
2 Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation
10.1016/j.mencom.2023.06.032
Published 2023-06-13
Communication , Volume 33, Issue 4, 539-542
4
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Tsyganov D. V. et al. Synthesis and X-ray diffraction analysis of coenzyme Q derivatives obtained from natural polyalkoxyallylbenzenes // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 539-542.
GOST all authors (up to 50) Copy
Tsyganov D. V., Demchuk D. V., Adaeva O. I., Konyushkin L. D., Minyaev M. E., Khrustalev V. N., Semenov V. V. Synthesis and X-ray diffraction analysis of coenzyme Q derivatives obtained from natural polyalkoxyallylbenzenes // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 539-542.
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TY - JOUR
DO - 10.1016/j.mencom.2023.06.032
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.032
TI - Synthesis and X-ray diffraction analysis of coenzyme Q derivatives obtained from natural polyalkoxyallylbenzenes
T2 - Mendeleev Communications
AU - Tsyganov, Dmitry Vadimovich
AU - Demchuk, Dmitry Valentinovich
AU - Adaeva, Olga Igorevna
AU - Konyushkin, Leonid Dmitrievich
AU - Minyaev, Mikhail Evgenievich
AU - Khrustalev, Victor Nikolaevich
AU - Semenov, Victor Vladimirovich
PY - 2023
DA - 2023/06/13
PB - Mendeleev Communications
SP - 539-542
IS - 4
VL - 33
ER -
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@article{2023_Tsyganov,
author = {Dmitry Vadimovich Tsyganov and Dmitry Valentinovich Demchuk and Olga Igorevna Adaeva and Leonid Dmitrievich Konyushkin and Mikhail Evgenievich Minyaev and Victor Nikolaevich Khrustalev and Victor Vladimirovich Semenov},
title = {Synthesis and X-ray diffraction analysis of coenzyme Q derivatives obtained from natural polyalkoxyallylbenzenes},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.032},
number = {4},
pages = {539--542},
doi = {10.1016/j.mencom.2023.06.032}
}
MLA
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MLA Copy
Tsyganov, Dmitry Vadimovich, et al. “Synthesis and X-ray diffraction analysis of coenzyme Q derivatives obtained from natural polyalkoxyallylbenzenes.” Mendeleev Communications, vol. 33, no. 4, Jun. 2023, pp. 539-542. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.032.

Keywords

(methylenedioxy)benzaldehyde
allylbenzenes
Baeyer–Villiger rearrangement
coenzyme Q
formylation
oxidation.
polyalkoxyquinone

Abstract

A general synthetic access to methoxy analogues of coenzymes Q bearing functional substituents with various chain lengths at the quinone ring was developed using available natural (polymethoxy)(methylenedioxy)allylbenzenes. The Baeyer-Villiger rearrangement of (methylenedioxy)benzaldehydes into phenols followed by facile oxidation to quinones with the methylenedioxy moiety opening was identified as the key step in the synthesis of the target 1,4- and 1,2-polyalkoxyquinones

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