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Influence of xenon difluoride on the optical properties of fluorozirconate and fluorohafnate glasses

,  , 
Liudmila Victorovna Moiseeva 2
Liudmila Victorovna Moiseeva
, 
Ludmila Ivanovna Demina 3
Ludmila Ivanovna Demina
, 
Valeria Victorovna Vinokurova 1
Valeria Victorovna Vinokurova
, 
Leonid Aleksandrovich Vaimugin 1
Leonid Aleksandrovich Vaimugin
2 Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow, Russian Federation
3 A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
10.1016/j.mencom.2023.06.027
Published 2023-06-13
Communication , Volume 33, Issue 4, 525-527
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Brekhovskikh M. N. et al. Influence of xenon difluoride on the optical properties of fluorozirconate and fluorohafnate glasses // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 525-527.
GOST all authors (up to 50) Copy
Brekhovskikh M. N., Batygov S. K., Moiseeva L. V., Demina L. I., Vinokurova V. V., Vaimugin L. A. Influence of xenon difluoride on the optical properties of fluorozirconate and fluorohafnate glasses // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 525-527.
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TY - JOUR
DO - 10.1016/j.mencom.2023.06.027
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.027
TI - Influence of xenon difluoride on the optical properties of fluorozirconate and fluorohafnate glasses
T2 - Mendeleev Communications
AU - Brekhovskikh, Maria Nikolaevna
AU - Batygov, Sergey Khacheturovich
AU - Moiseeva, Liudmila Victorovna
AU - Demina, Ludmila Ivanovna
AU - Vinokurova, Valeria Victorovna
AU - Vaimugin, Leonid Aleksandrovich
PY - 2023
DA - 2023/06/13
PB - Mendeleev Communications
SP - 525-527
IS - 4
VL - 33
ER -
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@article{2023_Brekhovskikh,
author = {Maria Nikolaevna Brekhovskikh and Sergey Khacheturovich Batygov and Liudmila Victorovna Moiseeva and Ludmila Ivanovna Demina and Valeria Victorovna Vinokurova and Leonid Aleksandrovich Vaimugin},
title = {Influence of xenon difluoride on the optical properties of fluorozirconate and fluorohafnate glasses},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.027},
number = {4},
pages = {525--527},
doi = {10.1016/j.mencom.2023.06.027}
}
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Brekhovskikh, Maria Nikolaevna, et al. “Influence of xenon difluoride on the optical properties of fluorozirconate and fluorohafnate glasses.” Mendeleev Communications, vol. 33, no. 4, Jun. 2023, pp. 525-527. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.027.

Keywords

fluorohafnate glasses
fluoroxidizer
fluorozirconate glasses
OH¯ group
optical transmission.
XeF2

Abstract

To study the effect of xenon difluoride as a fluorinating agent on optical properties of glasses in ZBLAN (ZrF4-BaF2-LaF3-AlF3-NaF) and HBLAN (HfF4-BaF2-LaF3-AlF3-NaF) systems, their optical transmission in the range from UV to IR was investigated. The treatment of the initial fluorides with XeF2 was shown to lead to a broadening of the transmission region of the obtained glasses both in the UV and IR ranges. Moreover, the treatment of the batch with xenon difluoride leads to the removal of oxygen-containing impurities that absorb in the region of 2.8 μm.

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