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Thermodynamic characteristics of sodium ditungstate single crystal

Nata Ivanovna Matskevich 1
Nata Ivanovna Matskevich
, 
Veronika Dmitrievna Grigorieva 1
Veronika Dmitrievna Grigorieva
, 
Anna Nikolaevna Semerikova 1
Anna Nikolaevna Semerikova
, 
Vladimir Nikolaevich Shlegel 1
Vladimir Nikolaevich Shlegel
, 
Mariya Yuryevna Matskevich 1
Mariya Yuryevna Matskevich
, 
Olga Iosiphovna Anyfrieva 1
Olga Iosiphovna Anyfrieva
1 A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
10.1016/j.mencom.2023.06.026
Published 2023-06-13
Communication , Volume 33, Issue 4, 522-524
4
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Matskevich N. I. et al. Thermodynamic characteristics of sodium ditungstate single crystal // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 522-524.
GOST all authors (up to 50) Copy
Matskevich N. I., Grigorieva V. D., Semerikova A. N., Shlegel V. N., Matskevich M. Y., Anyfrieva O. I. Thermodynamic characteristics of sodium ditungstate single crystal // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 522-524.
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TY - JOUR
DO - 10.1016/j.mencom.2023.06.026
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.026
TI - Thermodynamic characteristics of sodium ditungstate single crystal
T2 - Mendeleev Communications
AU - Matskevich, Nata Ivanovna
AU - Grigorieva, Veronika Dmitrievna
AU - Semerikova, Anna Nikolaevna
AU - Shlegel, Vladimir Nikolaevich
AU - Matskevich, Mariya Yuryevna
AU - Anyfrieva, Olga Iosiphovna
PY - 2023
DA - 2023/06/13
PB - Mendeleev Communications
SP - 522-524
IS - 4
VL - 33
ER -
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@article{2023_Matskevich,
author = {Nata Ivanovna Matskevich and Veronika Dmitrievna Grigorieva and Anna Nikolaevna Semerikova and Vladimir Nikolaevich Shlegel and Mariya Yuryevna Matskevich and Olga Iosiphovna Anyfrieva},
title = {Thermodynamic characteristics of sodium ditungstate single crystal},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.026},
number = {4},
pages = {522--524},
doi = {10.1016/j.mencom.2023.06.026}
}
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Matskevich, Nata Ivanovna, et al. “Thermodynamic characteristics of sodium ditungstate single crystal.” Mendeleev Communications, vol. 33, no. 4, Jun. 2023, pp. 522-524. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.026.

Keywords

Czochralski technique
enthalpy of formation.
single crystal
sodium ditungstate
solution calorimetry

Abstract

The single crystal of Na2W2O7 has been grown by the low-temperature-gradient Czochralski technique. The thermo- dynamic properties (standard enthalpy of formation, lattice enthalpy and stabilization energy), the knowledge of which is necessary to improve the growth technology, have been measured using reaction calorimetry. It has been shown that in the Na2W2O7- Na2Mo2O7 series, the luminescence wavelength increases from 540 to 650 nm, respectively, along with a change in the lattice enthalpy from −49030 to −54730 kJ mol−1.

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