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Synthesis of diamantane from new polycyclic hydrocarbons C14 under the action of ionic liquids

Rishat Ishbirdovich Aminov 1
Rishat Ishbirdovich Aminov
1 Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
10.1016/j.mencom.2023.06.022
Published 2023-06-13
Communication , Volume 33, Issue 4, 509-511
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Aminov R. I. Synthesis of diamantane from new polycyclic hydrocarbons C14 under the action of ionic liquids // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 509-511.
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Aminov R. I. Synthesis of diamantane from new polycyclic hydrocarbons C14 under the action of ionic liquids // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 509-511.
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TY - JOUR
DO - 10.1016/j.mencom.2023.06.022
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.022
TI - Synthesis of diamantane from new polycyclic hydrocarbons C14 under the action of ionic liquids
T2 - Mendeleev Communications
AU - Aminov, Rishat Ishbirdovich
PY - 2023
DA - 2023/06/13
PB - Mendeleev Communications
SP - 509-511
IS - 4
VL - 33
ER -
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@article{2023_Aminov,
author = {Rishat Ishbirdovich Aminov},
title = {Synthesis of diamantane from new polycyclic hydrocarbons C14 under the action of ionic liquids},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.022},
number = {4},
pages = {509--511},
doi = {10.1016/j.mencom.2023.06.022}
}
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Aminov, Rishat Ishbirdovich. “Synthesis of diamantane from new polycyclic hydrocarbons C14 under the action of ionic liquids.” Mendeleev Communications, vol. 33, no. 4, Jun. 2023, pp. 509-511. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.022.

Keywords

cyclopropanation
diamantane
ionic liquids.
isomerization
polycyclic hydrocarbons

Abstract

Diamantane was obtained by skeletal rearrangement of three new polycyclic hydrocarbons C14H18, C14H20 and C14H22 under the action of aluminate ionic liquids. For the successful isomerization of hydrocarbon C14H22 containing two hydrogen atoms more, the addition of Pd/C to the reaction medium is necessary.

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