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Electrochemical investigation of a photochromic spiropyran containing a pyrrolidinofullerene moiety

Aleksandr Aleksandrovich Nekrasov 1
Aleksandr Aleksandrovich Nekrasov
, 
Natalia Vladimirovna Nekrasova 1
Natalia Vladimirovna Nekrasova
, 
Michael A Savel'ev 2
Michael A Savel'ev
, 
Artur Albertovich Khuzin 3
Artur Albertovich Khuzin
, 
Valerii Aleksandrovich Barachevskii 2, 4
Valerii Aleksandrovich Barachevskii
, 
Artur Radisovich Tulyabaev 3
Artur Radisovich Tulyabaev
, 
Airat Ramilevich Tuktarov 3
Airat Ramilevich Tuktarov
1 A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
2 Interdepartmental Center for Analytical Research in Physics, Chemistry and Biology of the Presidium of the Russian Academy of Sciences
3 Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
4 Photochemistry Center, FSRC ‘Crystallography and Photonics’, Russian Academy of Sciences, Moscow, Russian Federation
10.1016/j.mencom.2023.06.021
Published 2023-06-13
Communication , Volume 33, Issue 4, 505-508
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Nekrasov A. A. et al. Electrochemical investigation of a photochromic spiropyran containing a pyrrolidinofullerene moiety // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 505-508.
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Nekrasov A. A., Nekrasova N. V., Savel'ev M. A., Khuzin A. A., Barachevskii V. A., Tulyabaev A. R., Tuktarov A. R. Electrochemical investigation of a photochromic spiropyran containing a pyrrolidinofullerene moiety // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 505-508.
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TY - JOUR
DO - 10.1016/j.mencom.2023.06.021
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.021
TI - Electrochemical investigation of a photochromic spiropyran containing a pyrrolidinofullerene moiety
T2 - Mendeleev Communications
AU - Nekrasov, Aleksandr Aleksandrovich
AU - Nekrasova, Natalia Vladimirovna
AU - Savel'ev, Michael A
AU - Khuzin, Artur Albertovich
AU - Barachevskii, Valerii Aleksandrovich
AU - Tulyabaev, Artur Radisovich
AU - Tuktarov, Airat Ramilevich
PY - 2023
DA - 2023/06/13
PB - Mendeleev Communications
SP - 505-508
IS - 4
VL - 33
ER -
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@article{2023_Nekrasov,
author = {Aleksandr Aleksandrovich Nekrasov and Natalia Vladimirovna Nekrasova and Michael A Savel'ev and Artur Albertovich Khuzin and Valerii Aleksandrovich Barachevskii and Artur Radisovich Tulyabaev and Airat Ramilevich Tuktarov},
title = {Electrochemical investigation of a photochromic spiropyran containing a pyrrolidinofullerene moiety},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.021},
number = {4},
pages = {505--508},
doi = {10.1016/j.mencom.2023.06.021}
}
MLA
Cite this
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Nekrasov, Aleksandr Aleksandrovich, et al. “Electrochemical investigation of a photochromic spiropyran containing a pyrrolidinofullerene moiety.” Mendeleev Communications, vol. 33, no. 4, Jun. 2023, pp. 505-508. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.021.

Keywords

[60]fullerene
cyclic voltammogram
electrochemical study.
HOMO–LUMO energy gap
pyrrolidinofullerene
spiropyrans

Abstract

Reversible transformations of a hybrid molecule based on [60]fullerene and a spiropyran moiety under conditions of combined photo- and electrochemical exposure were found. It has been established that the electrochemical oxidation of the UV-photoinduced colored form of the hybrid spiropyran in solution significantly accelerates the discoloration process and does not affect the fullerene part of the hybrid molecule. The research results are promising for designing a photo-electrochromic device that modulates electromagnetic radiation in the visible range of the spectrum.

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