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Chlorofullerenes with isomeric C86 carbon cages: C86(16)Cl16 and C86(17)Cl18,20

Shangfeng Yang 1
Shangfeng Yang
, 
1 Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, Hefei, China
2 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
10.1016/j.mencom.2023.06.020
Published 2023-06-13
Communication , Volume 33, Issue 4, 503-504
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Yang S., Troyanov S. I. Chlorofullerenes with isomeric C86 carbon cages: C86(16)Cl16 and C86(17)Cl18,20 // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 503-504.
GOST all authors (up to 50) Copy
Yang S., Troyanov S. I. Chlorofullerenes with isomeric C86 carbon cages: C86(16)Cl16 and C86(17)Cl18,20 // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 503-504.
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TY - JOUR
DO - 10.1016/j.mencom.2023.06.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.020
TI - Chlorofullerenes with isomeric C86 carbon cages: C86(16)Cl16 and C86(17)Cl18,20
T2 - Mendeleev Communications
AU - Yang, Shangfeng
AU - Troyanov, Sergey Igorevich
PY - 2023
DA - 2023/06/13
PB - Mendeleev Communications
SP - 503-504
IS - 4
VL - 33
ER -
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@article{2023_Yang,
author = {Shangfeng Yang and Sergey Igorevich Troyanov},
title = {Chlorofullerenes with isomeric C86 carbon cages: C86(16)Cl16 and C86(17)Cl18,20},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.020},
number = {4},
pages = {503--504},
doi = {10.1016/j.mencom.2023.06.020}
}
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Yang, Shangfeng, and Sergey Igorevich Troyanov. “Chlorofullerenes with isomeric C86 carbon cages: C86(16)Cl16 and C86(17)Cl18,20.” Mendeleev Communications, vol. 33, no. 4, Jun. 2023, pp. 503-504. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.020.

Keywords

C86
chlorination
higher fullerenes
IPR isomers
structure elucidation.

Abstract

Chlorofullerenes C86(16)Cl16 and C86(17)Cl18,20 were prepared by chlorination of Cs-C86(16) and C2-C86(17), respectively, with VCl4 at 320-340 °C. An X-ray crystallo- graphic study with the use of synchrotron radiation revealed the chlorination patterns which show certain similarity due to only small differences between isomeric C86 cages.

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