Home / Publications / N-Isopropyl-N',N'-diphenyl-N-(silylmethyl)ureas: Synthesis and structure

N-Isopropyl-N',N'-diphenyl-N-(silylmethyl)ureas: Synthesis and structure

Nataliya Fedorovna Lazareva 1
Nataliya Fedorovna Lazareva
, 
Mikhail Andreevich Alekseev 1
Mikhail Andreevich Alekseev
, 
Irina Vladimirovna Sterkhova 1
Irina Vladimirovna Sterkhova
, 
Tatyana Valeryevna Rybalova 2
Tatyana Valeryevna Rybalova
10.1016/j.mencom.2023.06.019
Published 2023-06-13
Communication , Volume 33, Issue 4, 500-502
3
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Lazareva N. F. et al. N-Isopropyl-N',N'-diphenyl-N-(silylmethyl)ureas: Synthesis and structure // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 500-502.
GOST all authors (up to 50) Copy
Lazareva N. F., Alekseev M. A., Sterkhova I. V., Rybalova T. V. N-Isopropyl-N',N'-diphenyl-N-(silylmethyl)ureas: Synthesis and structure // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 500-502.
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TY - JOUR
DO - 10.1016/j.mencom.2023.06.019
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.019
TI - N-Isopropyl-N',N'-diphenyl-N-(silylmethyl)ureas: Synthesis and structure
T2 - Mendeleev Communications
AU - Lazareva, Nataliya Fedorovna
AU - Alekseev, Mikhail Andreevich
AU - Sterkhova, Irina Vladimirovna
AU - Rybalova, Tatyana Valeryevna
PY - 2023
DA - 2023/06/13
PB - Mendeleev Communications
SP - 500-502
IS - 4
VL - 33
ER -
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@article{2023_Lazareva,
author = {Nataliya Fedorovna Lazareva and Mikhail Andreevich Alekseev and Irina Vladimirovna Sterkhova and Tatyana Valeryevna Rybalova},
title = {N-Isopropyl-N',N'-diphenyl-N-(silylmethyl)ureas: Synthesis and structure},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.019},
number = {4},
pages = {500--502},
doi = {10.1016/j.mencom.2023.06.019}
}
MLA
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Lazareva, Nataliya Fedorovna, et al. “N-Isopropyl-N',N'-diphenyl-N-(silylmethyl)ureas: Synthesis and structure.” Mendeleev Communications, vol. 33, no. 4, Jun. 2023, pp. 500-502. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.019.

Keywords

(O–Si) chelates
dative bond
N'
N'-diphenyl-N-(silylmethyl)ureas
NMR
organosilicon compounds
pentacoordinate silicon atom
X-ray.

Abstract

New N-isopropyl-N',N'-diphenyl-N-(silylmethyl)ureas were obtained, and their structure was explored by 1H, 13C, 29Si NMR spectroscopy and X-ray analysis. These results have shown that N-isopropyl-N', N'-diphenyl-N-[(fluorosilyl)-methyl]ureas exist as (O-Si) chelates with intramolecular dative bond C=O→Si.

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