Home / Publications / Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2]

Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2]

Ilya Arkad'evich Yakushev 1
Ilya Arkad'evich Yakushev
, 
Nadezhda K Ogarkova 1, 2
Nadezhda K Ogarkova
, 
Evgeny Vladimirovich Khramov 1, 3
Evgeny Vladimirovich Khramov
, 
Nadezhda Sergeevna Smirnova 1, 4
Nadezhda Sergeevna Smirnova
, 
Maria Yurievna Nesterenko 1
Maria Yurievna Nesterenko
, 
Natalia Victorovna Cherkashina 1
Natalia Victorovna Cherkashina
, 
Alexander G Medvedev 1
Alexander G Medvedev
,  , 
Michael Natanovich Vargaftik 1
Michael Natanovich Vargaftik
, 
Anna Sergeevna Popova 1, 2
Anna Sergeevna Popova
2 Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation
3 National Research Centre 'Kurchatov Institute', Moscow, Russian Federation
10.1016/j.mencom.2023.06.015
Published 2023-06-13
Communication , Volume 33, Issue 4, 487-490
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Yakushev I. A. et al. Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2] // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 487-490.
GOST all authors (up to 50) Copy
Yakushev I. A., Ogarkova N. K., Khramov E. V., Smirnova N. S., Nesterenko M. Y., Cherkashina N. V., Medvedev A. G., Panina M. V., Vargaftik M. N., Popova A. S. Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2] // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 487-490.
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TY - JOUR
DO - 10.1016/j.mencom.2023.06.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.015
TI - Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2]
T2 - Mendeleev Communications
AU - Yakushev, Ilya Arkad'evich
AU - Ogarkova, Nadezhda K
AU - Khramov, Evgeny Vladimirovich
AU - Smirnova, Nadezhda Sergeevna
AU - Nesterenko, Maria Yurievna
AU - Cherkashina, Natalia Victorovna
AU - Medvedev, Alexander G
AU - Panina, Maria Viktorovna
AU - Vargaftik, Michael Natanovich
AU - Popova, Anna Sergeevna
PY - 2023
DA - 2023/06/13
PB - Mendeleev Communications
SP - 487-490
IS - 4
VL - 33
ER -
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@article{2023_Yakushev,
author = {Ilya Arkad'evich Yakushev and Nadezhda K Ogarkova and Evgeny Vladimirovich Khramov and Nadezhda Sergeevna Smirnova and Maria Yurievna Nesterenko and Natalia Victorovna Cherkashina and Alexander G Medvedev and Maria Viktorovna Panina and Michael Natanovich Vargaftik and Anna Sergeevna Popova},
title = {Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2]},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.015},
number = {4},
pages = {487--490},
doi = {10.1016/j.mencom.2023.06.015}
}
MLA
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Yakushev, Ilya Arkad'evich, et al. “Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2].” Mendeleev Communications, vol. 33, no. 4, Jun. 2023, pp. 487-490. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.015.

Keywords

ferrocenecarboxylic acid
platinum complexes
platinum–iron intermetallic compounds.
thermolysis
X-ray absorption spectroscopy

Abstract

Novel square-planar Pt-based heterometallic complexes with ferrocenecarboxylic acid were prepared in two steps from (tetrapyridine)platinum diacetate [PtPy4](OAc)2. The crystal structure of [PtPy4](FcCOO)2 and [PtPy2(FcCOO)2] was established by single crystal X-ray diffraction. Subsequent thermal transformation of a trinuclear compound [PtPy2(FcCOO)2] to a bimetallic Pt-Fe phase was studied by XAFS techniques.

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