Keywords
combustion calorimetry.
N-(chloromethyl)nitramines
nitramines
propargyl ethers
X-ray
Abstract
The syntheses and characterization of novel propargyl ethers of N-(hydroxymethyl)nitramines that contain from one to four nitramine units are reported. All nitramine-functionalized ethers were well characterized by IR and multinuclear NMR spectroscopy as well as CHN analysis, and the X-ray crystal structures of two of them are described. For ethers bearing two or three nitramine units, the standard molar enthalpies of formation at 298.15 K were determined from the experimental standard molar energies of combustion in oxygen measured by static bomb combustion calorimetry
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