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Application of NO2/supercritical CO2 system for safe and selective nitration of adamantanes and tertiary alkyl bromides

Alexandra V Budkova 1, 2
Alexandra V Budkova
, 
Vladislav Gennadievich Merkulov 1, 2
Vladislav Gennadievich Merkulov
, 
Roman E Ivanov 1
Roman E Ivanov
,  , 
Ilya Vladimirovich Kuchurov 1
Ilya Vladimirovich Kuchurov
, 
Sergei Grigorievich Zlotin 1
Sergei Grigorievich Zlotin
2 D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
10.1016/j.mencom.2023.06.006
Published 2023-06-13
Communication , Volume 33, Issue 4, 461-462
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Budkova A. V. et al. Application of NO2/supercritical CO2 system for safe and selective nitration of adamantanes and tertiary alkyl bromides // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 461-462.
GOST all authors (up to 50) Copy
Budkova A. V., Merkulov V. G., Ivanov R. E., Zharkov M. N., Kuchurov I. V., Zlotin S. G. Application of NO2/supercritical CO2 system for safe and selective nitration of adamantanes and tertiary alkyl bromides // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 461-462.
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TY - JOUR
DO - 10.1016/j.mencom.2023.06.006
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.006
TI - Application of NO2/supercritical CO2 system for safe and selective nitration of adamantanes and tertiary alkyl bromides
T2 - Mendeleev Communications
AU - Budkova, Alexandra V
AU - Merkulov, Vladislav Gennadievich
AU - Ivanov, Roman E
AU - Zharkov, Mikhail Nikolaevich
AU - Kuchurov, Ilya Vladimirovich
AU - Zlotin, Sergei Grigorievich
PY - 2023
DA - 2023/06/13
PB - Mendeleev Communications
SP - 461-462
IS - 4
VL - 33
ER -
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@article{2023_Budkova,
author = {Alexandra V Budkova and Vladislav Gennadievich Merkulov and Roman E Ivanov and Mikhail Nikolaevich Zharkov and Ilya Vladimirovich Kuchurov and Sergei Grigorievich Zlotin},
title = {Application of NO2/supercritical CO2 system for safe and selective nitration of adamantanes and tertiary alkyl bromides},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.006},
number = {4},
pages = {461--462},
doi = {10.1016/j.mencom.2023.06.006}
}
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MLA Copy
Budkova, Alexandra V., et al. “Application of NO2/supercritical CO2 system for safe and selective nitration of adamantanes and tertiary alkyl bromides.” Mendeleev Communications, vol. 33, no. 4, Jun. 2023, pp. 461-462. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.06.006.

Keywords

adamantane
nitrates
nitroalkanes
nitrogen dioxide
supercritical carbon dioxide
tert-alkyl bromides.

Abstract

A concise safe approach for selective nitration and nitroxylation of tert-alkanes, in particular adamantane, and tert-alkyl bromides utilizing NO2 in supercritical CO2 medium has been established. Major reaction products were tert-alkyl nitro compounds and tert-alkyl nitrates depending on the reaction conditions.

References

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