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Spectral characteristics of ethylene sorbed by silver-containing ionic liquids studied by in situ ATR-FTIR spectroscopy

, 
Sergey Alexandrovich Prikhod’ko 1
Sergey Alexandrovich Prikhod’ko
,  , 
Oleg Nikolaevich Martyanov 1
Oleg Nikolaevich Martyanov
1 G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
10.1016/j.mencom.2023.04.040
Published 2023-04-13
Communication , Volume 33, Issue 3, 425-427
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Kovalev E. P. et al. Spectral characteristics of ethylene sorbed by silver-containing ionic liquids studied by in situ ATR-FTIR spectroscopy // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 425-427.
GOST all authors (up to 50) Copy
Kovalev E. P., Prikhod’ko S. A., Shalygin A. S., Martyanov O. N. Spectral characteristics of ethylene sorbed by silver-containing ionic liquids studied by in situ ATR-FTIR spectroscopy // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 425-427.
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TY - JOUR
DO - 10.1016/j.mencom.2023.04.040
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.040
TI - Spectral characteristics of ethylene sorbed by silver-containing ionic liquids studied by in situ ATR-FTIR spectroscopy
T2 - Mendeleev Communications
AU - Kovalev, Evgeny Pavlovich
AU - Prikhod’ko, Sergey Alexandrovich
AU - Shalygin, Anton Sergeevich
AU - Martyanov, Oleg Nikolaevich
PY - 2023
DA - 2023/04/13
PB - Mendeleev Communications
SP - 425-427
IS - 3
VL - 33
ER -
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@article{2023_Kovalev,
author = {Evgeny Pavlovich Kovalev and Sergey Alexandrovich Prikhod’ko and Anton Sergeevich Shalygin and Oleg Nikolaevich Martyanov},
title = {Spectral characteristics of ethylene sorbed by silver-containing ionic liquids studied by in situ ATR-FTIR spectroscopy},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.040},
number = {3},
pages = {425--427},
doi = {10.1016/j.mencom.2023.04.040}
}
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Kovalev, Evgeny Pavlovich, et al. “Spectral characteristics of ethylene sorbed by silver-containing ionic liquids studied by in situ ATR-FTIR spectroscopy.” Mendeleev Communications, vol. 33, no. 3, Apr. 2023, pp. 425-427. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.040.

Keywords

absorption
ATR-FTIR spectroscopy
ethylene
ionic liquids
silver
π-complex.

Abstract

The spectral characteristics of ethylene absorbed by ionic liquids (ILs) containing silver ions were studied by in situ ATR-FTIR spectroscopy at high pressure. Three different states of ethylene were observed based on the band shift of out-of-plane bending vibrations (ωCH2) due to van der Waals interactions, hydrogen bonds, and π-complex formation with silver ions. Thus, ethylene can be used as an IR-sensitive probe molecule for characterizing interactions with ILs and other substances.

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