Formation of active phases of Fe/C, Cr/C and Fe-Cr/C catalysts in oxidative dehydrogenation of ethane

Mishanin, Igor Igorevich; Bogdan, Tatiana Veniaminovna; Smirnov, Aleksey Vladimirovich; Chernavskii, Petr Aleksandrovich; Kuznetsova, Natalia N; Bogdan, Viktor Ignat'evich

doi:10.1016/j.mencom.2023.04.039

Home / Publications / Formation of active phases of Fe/C, Cr/C and Fe-Cr/C catalysts in oxidative dehydrogenation of ethane

Formation of active phases of Fe/C, Cr/C and Fe-Cr/C catalysts in oxidative dehydrogenation of ethane

Igor Igorevich Mishanin ^{1, 2}

Igor Igorevich Mishanin

,

Tatiana Veniaminovna Bogdan ^{1, 2}

Tatiana Veniaminovna Bogdan

,

Aleksey Vladimirovich Smirnov ^{1, 2}

Aleksey Vladimirovich Smirnov

,

Petr Aleksandrovich Chernavskii ^{1, 2}

Petr Aleksandrovich Chernavskii

,

Natalia N Kuznetsova ²

Natalia N Kuznetsova

,

Viktor Ignat'evich Bogdan ¹

Viktor Ignat'evich Bogdan

¹ N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

² Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

10.1016/j.mencom.2023.04.039

Copy DOI

Published 2023-04-13

Communication , Volume 33, Issue 3, 422-424

View PDF

Supporting information

Graphical abstract

12

Share

Cite this

GOST

|

Cite this

GOST Copy

Mishanin I. I. et al. Formation of active phases of Fe/C, Cr/C and Fe-Cr/C catalysts in oxidative dehydrogenation of ethane // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 422-424.

GOST all authors (up to 50) Copy

Mishanin I. I., Bogdan T. V., Smirnov A. V., Chernavskii P. A., Kuznetsova N. N., Bogdan V. I. Formation of active phases of Fe/C, Cr/C and Fe-Cr/C catalysts in oxidative dehydrogenation of ethane // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 422-424.

RIS

|

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.mencom.2023.04.039

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.039

TI - Formation of active phases of Fe/C, Cr/C and Fe-Cr/C catalysts in oxidative dehydrogenation of ethane

T2 - Mendeleev Communications

AU - Mishanin, Igor Igorevich

AU - Bogdan, Tatiana Veniaminovna

AU - Smirnov, Aleksey Vladimirovich

AU - Chernavskii, Petr Aleksandrovich

AU - Kuznetsova, Natalia N

AU - Bogdan, Viktor Ignat'evich

PY - 2023

DA - 2023/04/13

PB - Mendeleev Communications

SP - 422-424

IS - 3

VL - 33

ER -

BibTex

|

Cite this

BibTex (up to 50 authors) Copy

@article{2023_Mishanin,

author = {Igor Igorevich Mishanin and Tatiana Veniaminovna Bogdan and Aleksey Vladimirovich Smirnov and Petr Aleksandrovich Chernavskii and Natalia N Kuznetsova and Viktor Ignat'evich Bogdan},

title = {Formation of active phases of Fe/C, Cr/C and Fe-Cr/C catalysts in oxidative dehydrogenation of ethane},

journal = {Mendeleev Communications},

year = {2023},

volume = {33},

publisher = {Mendeleev Communications},

month = {Apr},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.039},

number = {3},

pages = {422--424},

doi = {10.1016/j.mencom.2023.04.039}

}

MLA

Cite this

MLA Copy

Mishanin, Igor Igorevich, et al. “Formation of active phases of Fe/C, Cr/C and Fe-Cr/C catalysts in oxidative dehydrogenation of ethane.” Mendeleev Communications, vol. 33, no. 3, Apr. 2023, pp. 422-424. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.039.

Keywords

carbon dioxide

Cr/C catalyst

Fe–Cr/C catalyst

Fe/C catalyst

magnetometry

oxidative dehydrogenation of ethane into ethylene

TEM.

XRD

Abstract

The oxidative dehydrogenation of ethane into ethylene using CO2 as an oxidant at temperatures of 650-750 °C was carried out over Fe/C, Cr/C and Fe-Cr/C catalysts deposited on a carbon support. Before and after the reaction the catalysts were investigated by X-ray powder diffraction (XRD), in situ magnetometry and transmission electron microscopy methods. The correlation between activity of Fe/C, Cr/C and Fe-Cr/C catalytic systems and their phase composition was established.

References

.

10.1070/RCR4932

Supercritical fluids in chemistry

Alekseev E.S., Alentiev A.Y., Belova A.S., Bogdan V.I., Bogdan T.V., Bystrova A.V., Gafarova E.R., Golubeva E.N., Grebenik E.A., Gromov O.I., Davankov V.A., Zlotin S.G., Kiselev M.G., Koklin A.E., Kononevich Y.N., et. al.

Russian Chemical Reviews, 2020

.

10.1070/rc2011v080n06abeh004187

Magnetometric methods of investigation of supported catalysts

Chernavskii P.A., Pankina G.V., Lunin V.V.

Russian Chemical Reviews, 2011

.

10.1016/j.apcata.2019.04.027

NAP-XPS and in situ XRD study of the stability of Bi-modified MoVNbTeO catalysts for oxidative dehydrogenation of ethane

Svintsitskiy D.A., Kardash T.Y., Lazareva E.V., Saraev A.A., Derevyannikova E.A., Vorokhta M., Šmíd B., Bondareva V.M.

Applied Catalysis A: General, 2019

.

10.1016/j.mencom.2019.07.034

Advantages of ethane oxidative dehydrogenation on the MoVNbTeO catalyst under elevated pressure

Mishanin I.I., Bogdan V.I.

Mendeleev Communications, 2019

.

10.1016/j.energy.2005.04.001

Olefins from conventional and heavy feedstocks: Energy use in steam cracking and alternative processes

REN T., PATEL M., BLOK K.

Energy, 2006

.

10.3390/catal10040418

Propane Oxidative Dehydrogenation on Vanadium-Based Catalysts under Oxygen-Free Atmospheres

Rostom S., de Lasa H.

Catalysts, 2020

.

10.1039/d1cs01036k

Light olefin synthesis from a diversity of renewable and fossil feedstocks: state-of the-art and outlook

Chernyak S.A., Corda M., Dath J., Ordomsky V.V., Khodakov A.Y.

Chemical Society Reviews, 2022

.

10.1016/S0926-860X(99)00450-0

Dehydrogenation of ethane with carbon dioxide over supported chromium oxide catalysts

Wang S., Murata K., Hayakawa T., Hamakawa S., Suzuki K.

Applied Catalysis A: General, 2000

.

10.1016/j.jcat.2022.06.021

Ethane oxidative dehydrogenation by CO2 over stable CsRu/CeO2 catalyst

Wang X., Wang Y., Robinson B., Wang Q., Hu J.

Journal of Catalysis, 2022

.

10.1016/j.fuproc.2018.04.037

Silica-doped TiO2 as support of gallium oxide for dehydrogenation of ethane with CO2

Lei T., Cheng Y., Miao C., Hua W., Yue Y., Gao Z.

Fuel Processing Technology, 2018

.

10.1016/j.cattod.2018.04.047

Oxidative dehydrogenation of ethane with CO2 over CrOx catalysts supported on Al2O3, ZrO2, CeO2 and CexZr1-xO2

Bugrova T.A., Dutov V.V., Svetlichnyi V.A., Cortés Corberán V., Mamontov G.V.

Catalysis Today, 2019

.

10.1016/j.mencom.2020.05.033

In situ CO2 reactivation of FeCrO /C catalyst in the oxidative dehydrogenation of ethane to ethylene

Mishanin I.I., Bogdan V.I.

Mendeleev Communications, 2020

.

10.1016/j.jcou.2021.101499

Simultaneous production of ethylene and hydrogen through carbon-dioxide-assisted conversion of ethane over cobalt-molybdenum catalysts

Bakhtyari A., Zafarnak S., Taghvaei H., Rahimpour M.R., Iulianelli A.

Journal of CO2 Utilization, 2021

.

10.1016/j.apcata.2021.118242

The nickel-support interaction as determining factor of the selectivity to ethylene in the oxidative dehydrogenation of ethane over nickel oxide/alumina catalysts

Abdelbaki Y., de Arriba A., Solsona B., Delgado D., García-González E., Issaadi R., López Nieto J.M.

Applied Catalysis A: General, 2021

.

10.1016/j.cej.2022.137184

Design of highly selective heterogeneous catalyst for CO2-mediated ethane oxidative dehydrogenation based on nonoxidative catalysis in stainless-steel reactor

Mishanin I.I., Bogdan T.V., Koklin A.E., Bogdan V.I.

Chemical Engineering Journal, 2022

.

10.1016/j.fuel.2021.122698

Dehydrogenation of propane in the presence of CO2 on GaOx/SiO2 catalyst: Influence of the texture characteristics of the support

Tedeeva M.A., Kustov A.L., Pribytkov P.V., Kapustin G.I., Leonov A.V., Tkachenko O.P., Tursunov O.B., Evdokimenko N.D., Kustov L.M.

Fuel, 2022