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Radiolytic redistribution of H and O atoms in acetylacetone

Daria Aleksandrovna Uchkina 1
Daria Aleksandrovna Uchkina
, 
Alexandr Vladimirovich Ponomarev 1
Alexandr Vladimirovich Ponomarev
1 A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russian Federation
10.1016/j.mencom.2023.04.029
Published 2023-04-13
Communication , Volume 33, Issue 3, 390-392
3
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Uchkina D. A., Ponomarev A. V. Radiolytic redistribution of H and O atoms in acetylacetone // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 390-392.
GOST all authors (up to 50) Copy
Uchkina D. A., Ponomarev A. V. Radiolytic redistribution of H and O atoms in acetylacetone // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 390-392.
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TY - JOUR
DO - 10.1016/j.mencom.2023.04.029
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.029
TI - Radiolytic redistribution of H and O atoms in acetylacetone
T2 - Mendeleev Communications
AU - Uchkina, Daria Aleksandrovna
AU - Ponomarev, Alexandr Vladimirovich
PY - 2023
DA - 2023/04/13
PB - Mendeleev Communications
SP - 390-392
IS - 3
VL - 33
ER -
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@article{2023_Uchkina,
author = {Daria Aleksandrovna Uchkina and Alexandr Vladimirovich Ponomarev},
title = {Radiolytic redistribution of H and O atoms in acetylacetone},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.029},
number = {3},
pages = {390--392},
doi = {10.1016/j.mencom.2023.04.029}
}
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Uchkina, Daria Aleksandrovna, and Alexandr Vladimirovich Ponomarev. “Radiolytic redistribution of H and O atoms in acetylacetone.” Mendeleev Communications, vol. 33, no. 3, Apr. 2023, pp. 390-392. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.029.

Keywords

4-dione
4-hydroxypent-3-en-2-one
acetylacetone
boiling
isomers.
pentane-2
proton transfer
radical cation
radiolysis

Abstract

Compared to ambient conditions, radiolysis of boiling acetylacetone almost halved the yield of C-OH bond cleavage and doubled the redistribution of H atoms

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