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Improvement of Li/Mg monovalent ion selectivity of cation-exchange membranes by incorporation of cerium or zirconium phosphate particles

Andrey Dmitrievich Manin 1, 2
Andrey Dmitrievich Manin
, 
Daniel Vladimirovich Golubenko 1
Daniel Vladimirovich Golubenko
, 
Polina Anatolievna Yurova 1, 2
Polina Anatolievna Yurova
, 
Andrei Borisovich Yaroslavtsev 1, 2
Andrei Borisovich Yaroslavtsev
2 National Research University Higher School of Economics (HSE University), Moscow, Russian Federation
10.1016/j.mencom.2023.04.022
Published 2023-04-13
Communication , Volume 33, Issue 3, 365-367
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Manin A. D. et al. Improvement of Li/Mg monovalent ion selectivity of cation-exchange membranes by incorporation of cerium or zirconium phosphate particles // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 365-367.
GOST all authors (up to 50) Copy
Manin A. D., Golubenko D. V., Yurova P. A., Yaroslavtsev A. B. Improvement of Li/Mg monovalent ion selectivity of cation-exchange membranes by incorporation of cerium or zirconium phosphate particles // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 365-367.
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TY - JOUR
DO - 10.1016/j.mencom.2023.04.022
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.022
TI - Improvement of Li/Mg monovalent ion selectivity of cation-exchange membranes by incorporation of cerium or zirconium phosphate particles
T2 - Mendeleev Communications
AU - Manin, Andrey Dmitrievich
AU - Golubenko, Daniel Vladimirovich
AU - Yurova, Polina Anatolievna
AU - Yaroslavtsev, Andrei Borisovich
PY - 2023
DA - 2023/04/13
PB - Mendeleev Communications
SP - 365-367
IS - 3
VL - 33
ER -
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@article{2023_Manin,
author = {Andrey Dmitrievich Manin and Daniel Vladimirovich Golubenko and Polina Anatolievna Yurova and Andrei Borisovich Yaroslavtsev},
title = {Improvement of Li/Mg monovalent ion selectivity of cation-exchange membranes by incorporation of cerium or zirconium phosphate particles},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.022},
number = {3},
pages = {365--367},
doi = {10.1016/j.mencom.2023.04.022}
}
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Manin, Andrey Dmitrievich, et al. “Improvement of Li/Mg monovalent ion selectivity of cation-exchange membranes by incorporation of cerium or zirconium phosphate particles.” Mendeleev Communications, vol. 33, no. 3, Apr. 2023, pp. 365-367. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.022.

Keywords

cerium phosphate.
hybrid membranes
ion-exchange membranes
lithium
modification
Selectivity
zirconium phosphate

Abstract

To improve the selectivity of cation-exchange membranes to the transfer of lithium with respect to magnesium during the electrodialysis desalination of lithium and magnesium sulfates solutions, the surface of a commercial cation-exchange membrane based on sulfated polystyrene was modified with cerium(III, IV) and zirconium phosphates. Upon incorporation of phosphate particles, the Li/Mg selectivity coefficients of the membranes increased up to 113%.

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