Home / Publications / Polymer-analogous transformations of poly(N-vinylpyrrolidone) to produce new complexing macromolecular systems

Polymer-analogous transformations of poly(N-vinylpyrrolidone) to produce new complexing macromolecular systems

Arthur Aleksandrovich Puzyrkov 1, 2
Arthur Aleksandrovich Puzyrkov
, 
Ekaterina Aleksandrovna Popova 1, 3
Ekaterina Aleksandrovna Popova
, 
Artem Alexandrovich Selyutin 1, 4
Artem Alexandrovich Selyutin
, 
Alexey Vladimirovich Eremin 1
Alexey Vladimirovich Eremin
1 Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russian Federation
2 Saint-Petersburg State University of Industrial Technologies and Design, St. Petersburg, Russian Federation
3 St. Petersburg State Institute of Technology (Technical University), St. Petersburg, Russian Federation
4 Institute of Earth Sciences, St. Petersburg State University, St. Petersburg, Russian Federation
10.1016/j.mencom.2023.04.021
Published 2023-04-13
Communication , Volume 33, Issue 3, 362-364
4
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Puzyrkov A. A. et al. Polymer-analogous transformations of poly(N-vinylpyrrolidone) to produce new complexing macromolecular systems // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 362-364.
GOST all authors (up to 50) Copy
Puzyrkov A. A., Popova E. A., Selyutin A. A., Eremin A. V. Polymer-analogous transformations of poly(N-vinylpyrrolidone) to produce new complexing macromolecular systems // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 362-364.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2023.04.021
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.021
TI - Polymer-analogous transformations of poly(N-vinylpyrrolidone) to produce new complexing macromolecular systems
T2 - Mendeleev Communications
AU - Puzyrkov, Arthur Aleksandrovich
AU - Popova, Ekaterina Aleksandrovna
AU - Selyutin, Artem Alexandrovich
AU - Eremin, Alexey Vladimirovich
PY - 2023
DA - 2023/04/13
PB - Mendeleev Communications
SP - 362-364
IS - 3
VL - 33
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2023_Puzyrkov,
author = {Arthur Aleksandrovich Puzyrkov and Ekaterina Aleksandrovna Popova and Artem Alexandrovich Selyutin and Alexey Vladimirovich Eremin},
title = {Polymer-analogous transformations of poly(N-vinylpyrrolidone) to produce new complexing macromolecular systems},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.021},
number = {3},
pages = {362--364},
doi = {10.1016/j.mencom.2023.04.021}
}
MLA
Cite this
MLA Copy
Puzyrkov, Arthur Aleksandrovich, et al. “Polymer-analogous transformations of poly(N-vinylpyrrolidone) to produce new complexing macromolecular systems.” Mendeleev Communications, vol. 33, no. 3, Apr. 2023, pp. 362-364. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.021.

Keywords

complex-forming polymers
poly(N-vinylpyrrolidone)
polymer-analogous transformations
post-polymerization modification
pyridine-containing polymers
silver ion.
thiourea

Abstract

A new polymer-analogous transformations of poly(N-vinylpyrrolidone) was used to prepare new complex-forming macromolecular systems containing thiourea and thio-semicarbazone sites. Two variants of modification were realized, namely, the method including the preliminary in situ activation of nucleophilic centres of the polymer amide fragments with dimethyl sulfate followed by introducing nucleophilic agents into the system, and the method including partial hydrolysis of poly(N-vinylpyrrolidone) followed by the amide coupling. The obtained modified polymeric materials react with silver ions in aqueous solution.

References

.
Kurmaz S.V., Fadeeva N.V., Skripets J.A., Komendant R.I., Ignatiev V.M., Emel'yanova N.S., Soldatova Y.V., Faingold I.I., Poletaeva D.A., Kotelnikova R.A.
Mendeleev Communications, 2022
.
Convenient Preparation of 68Ga-Based PET-Radiopharmaceuticals at Room Temperature
Velikyan I., Maecke H., Langstrom B.
Bioconjugate Chemistry, 2008
.
Ring opening in lactam polymers
Conix A., Smets G.
Journal of Polymer Science, 1955
.
Polyvinylpyrrolidone–drug conjugate: synthesis and release mechanism
D'Souza A.J., Schowen R.L., Topp E.M.
Journal of Controlled Release, 2004
.
Metal-containing and related polymers for biomedical applications.
Yan Y., Zhang J., Ren L., Tang C.
Chemical Society Reviews, 2016
.
Synthesis of New Thiourea-Metal Complexes with Promising Anticancer Properties
Canudo-Barreras G., Ortego L., Izaga A., Marzo I., Herrera R.P., Gimeno M.C.
Molecules, 2021
.
Gallium(III) and Iron(III) Complexes of α-N-Heterocyclic Thiosemicarbazones:  Synthesis, Characterization, Cytotoxicity, and Interaction with Ribonucleotide Reductase
Kowol C.R., Berger R., Eichinger R., Roller A., Jakupec M.A., Schmidt P.P., Arion V.B., Keppler B.K.
Journal of Medicinal Chemistry, 2007
.
Complexes of Transition Metals Based on Amino Acid Derivatives of Epoxy-Containing Poly-N-Vinylpyrrolidone
Tashmukhamedov R.I., Klyagina M.V., Khvostova V.Y., Goryachaya A.V., Shtil'man M.I., Tsatsakis A.M.
International Polymer Science and Technology, 2009
.
PVP (Polyvinylpyrrolidone)
Burnett C.L.
International Journal of Toxicology, 2017
.
A tumor-targeted polymer theranostics platform for positron emission tomography and fluorescence imaging
Koziolová E., Goel S., Chytil P., Janoušková O., Barnhart T.E., Cai W., Etrych T.
Nanoscale, 2017
.
Multifunctional Role of Polyvinylpyrrolidone in Pharmaceutical Formulations
Luo Y., Hong Y., Shen L., Wu F., Lin X.
AAPS PharmSciTech, 2021
.
Darzen's glycidic ester condensation reaction on poly(N-vinyl pyrrolidone)
Devarajan R., Arunachalam V., Kumaraswamy M.D., Tajuddin I., Joghee T.
Journal of Applied Polymer Science, 1992
.
A multi-functional polymeric carrier for simultaneous positron emission tomography imaging and combination therapy
Sun J., Sun L., Li J., Xu J., Wan Z., Ouyang Z., Liang L., Li S., Zeng D.
Acta Biomaterialia, 2018
.
Synthesis and evaluation of a novel urea-based 68 Ga-complex for imaging PSMA binding in tumor
Zha Z., Ploessl K., Choi S.R., Wu Z., Zhu L., Kung H.F.
Nuclear Medicine and Biology, 2018
.
Synthesis and antituberculosis activity of some N-pyridyl-N′-thiazolylhydrazine derivatives
Turan-Zitouni G., Kaplancıklı Z.A., Özdemir A.
European Journal of Medicinal Chemistry, 2010
.
Studies on 66,67Ga- and 199Tl-poly(N-vinylpyrrolidone) complexes
Lahiri S., Sarkar S.
Applied Radiation and Isotopes, 2007
.
An investigation of the interaction between polyvinylpyrrolidone and metal cations
Liu M., Yan X., Liu H., Yu W.
Reactive and Functional Polymers, 2000