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New type polyrotaxanes based on polyethyleneimine and α-cyclodextrin

, 
Mariya A Golovina 1
Mariya A Golovina
, 
Andrey Vitalievich Tenkovtsev 1
Andrey Vitalievich Tenkovtsev
1 Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russian Federation
10.1016/j.mencom.2023.04.020
Published 2023-04-13
Communication , Volume 33, Issue 3, 360-361
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Kurlykin M. P., Golovina M. A., Tenkovtsev A. V. New type polyrotaxanes based on polyethyleneimine and α-cyclodextrin // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 360-361.
GOST all authors (up to 50) Copy
Kurlykin M. P., Golovina M. A., Tenkovtsev A. V. New type polyrotaxanes based on polyethyleneimine and α-cyclodextrin // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 360-361.
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TY - JOUR
DO - 10.1016/j.mencom.2023.04.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.020
TI - New type polyrotaxanes based on polyethyleneimine and α-cyclodextrin
T2 - Mendeleev Communications
AU - Kurlykin, Mikhail Petrovich
AU - Golovina, Mariya A
AU - Tenkovtsev, Andrey Vitalievich
PY - 2023
DA - 2023/04/13
PB - Mendeleev Communications
SP - 360-361
IS - 3
VL - 33
ER -
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@article{2023_Kurlykin,
author = {Mikhail Petrovich Kurlykin and Mariya A Golovina and Andrey Vitalievich Tenkovtsev},
title = {New type polyrotaxanes based on polyethyleneimine and α-cyclodextrin},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.020},
number = {3},
pages = {360--361},
doi = {10.1016/j.mencom.2023.04.020}
}
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Kurlykin, Mikhail Petrovich, et al. “New type polyrotaxanes based on polyethyleneimine and α-cyclodextrin.” Mendeleev Communications, vol. 33, no. 3, Apr. 2023, pp. 360-361. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.020.

Keywords

acylation.
complexes
cyclodextrin
inclusion compounds
polyethyleneimine
polyoxazolines
polyrotaxane

Abstract

Functional polyrotaxanes of N-alkanoylpolyethyleneimine@ α-cyclodextrin type are synthesized by acylation of the polypseudorotaxane precursor, namely, a polyethylenimine@ α-cyclodextrin inclusion complex, with excess of carboxylic acid anhydrides. In the course of the processing, α-cyclo-dextrin moieties are also fully O-acylated. The introduction of acyl moieties into polyethyleneimine backbone prevents the expulsion of α-cyclodextrin rings from this backbone.

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