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(Cyclopentadienyl)neodymium borohydrides with auxiliary N3-heterocyclic ligands

Guzelia Il'yasovna Sadrtdinova 1, 2
Guzelia Il'yasovna Sadrtdinova
Daniil Arkadievich Bardonov 1, 2, 3
Daniil Arkadievich Bardonov
Konstantin Alexandrovich Lyssenko
Mikhail Evgenievich Minyaev
Ilya Eduardovich Nifant'ev
Dmitrii Mikhailovich Roitershtein
1 A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
2 National Research University Higher School of Economics (HSE University), Moscow, Russian Federation
4 G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation
5 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
Published 2023-04-13
CommunicationVolume 33, Issue 3, 357-359
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Sadrtdinova G. I. et al. (Cyclopentadienyl)neodymium borohydrides with auxiliary N3-heterocyclic ligands // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 357-359.
GOST all authors (up to 50) Copy
Sadrtdinova G. I., Bardonov D. A., Lyssenko K. A., Minyaev M. E., Nifant'ev I. E., Roitershtein D. M. (Cyclopentadienyl)neodymium borohydrides with auxiliary N3-heterocyclic ligands // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 357-359.
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TY - JOUR
DO - 10.1016/j.mencom.2023.04.019
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.019
TI - (Cyclopentadienyl)neodymium borohydrides with auxiliary N3-heterocyclic ligands
T2 - Mendeleev Communications
AU - Sadrtdinova, Guzelia Il'yasovna
AU - Bardonov, Daniil Arkadievich
AU - Lyssenko, Konstantin Alexandrovich
AU - Minyaev, Mikhail Evgenievich
AU - Nifant'ev, Ilya Eduardovich
AU - Roitershtein, Dmitrii Mikhailovich
PY - 2023
DA - 2023/04/13
PB - Mendeleev Communications
SP - 357-359
IS - 3
VL - 33
ER -
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@article{2023_Sadrtdinova,
author = {Guzelia Il'yasovna Sadrtdinova and Daniil Arkadievich Bardonov and Konstantin Alexandrovich Lyssenko and Mikhail Evgenievich Minyaev and Ilya Eduardovich Nifant'ev and Dmitrii Mikhailovich Roitershtein},
title = {(Cyclopentadienyl)neodymium borohydrides with auxiliary N3-heterocyclic ligands},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.019},
number = {3},
pages = {357--359},
doi = {10.1016/j.mencom.2023.04.019}
}
MLA
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Sadrtdinova, Guzelia Il'yasovna, et al. “(Cyclopentadienyl)neodymium borohydrides with auxiliary N3-heterocyclic ligands.” Mendeleev Communications, vol. 33, no. 3, Apr. 2023, pp. 357-359. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.019.

Keywords

borohydrides
crystal structure
cyclopentadienyl
lanthanide complexes
neodymium complexes
polymerization
ε-caprolactone..

Abstract

Mononuclear [CpNd(BH4)2L] borohydrides comprising L = 1,3,5-trimethyl-1,3,5-triazacyclohexane (Me3tach) and L = 1,4,7-trimethyl-1,4,7-triazacyclononane (Me3tacn) were obtained and structurally characterized. Their catalytic activity in coordination-insertion ring-opening poly-merization of ε-caprolactone was studied.

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