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Facile method for synthesis of mixed-cation halide perovskites by mild equilibrium conversion via iodine-mediated transport reaction in inert liquid media

, 
Anna Dmitrievna Riabova 1
Anna Dmitrievna Riabova
, 
Eugene Alekseevich Goodilin 1, 2
Eugene Alekseevich Goodilin
, 
Alexey Borisovich Tarasov 1, 2
Alexey Borisovich Tarasov
1 Department of Materials Science, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
2 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
10.1016/j.mencom.2023.04.004
Published 2023-04-13
Communication , Volume 33, Issue 3, 311-313
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Fateev S. A. et al. Facile method for synthesis of mixed-cation halide perovskites by mild equilibrium conversion via iodine-mediated transport reaction in inert liquid media // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 311-313.
GOST all authors (up to 50) Copy
Fateev S. A., Riabova A. D., Goodilin E. A., Tarasov A. B. Facile method for synthesis of mixed-cation halide perovskites by mild equilibrium conversion via iodine-mediated transport reaction in inert liquid media // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 311-313.
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TY - JOUR
DO - 10.1016/j.mencom.2023.04.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.004
TI - Facile method for synthesis of mixed-cation halide perovskites by mild equilibrium conversion via iodine-mediated transport reaction in inert liquid media
T2 - Mendeleev Communications
AU - Fateev, Sergey Anatol'evich
AU - Riabova, Anna Dmitrievna
AU - Goodilin, Eugene Alekseevich
AU - Tarasov, Alexey Borisovich
PY - 2023
DA - 2023/04/13
PB - Mendeleev Communications
SP - 311-313
IS - 3
VL - 33
ER -
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@article{2023_Fateev,
author = {Sergey Anatol'evich Fateev and Anna Dmitrievna Riabova and Eugene Alekseevich Goodilin and Alexey Borisovich Tarasov},
title = {Facile method for synthesis of mixed-cation halide perovskites by mild equilibrium conversion via iodine-mediated transport reaction in inert liquid media},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.004},
number = {3},
pages = {311--313},
doi = {10.1016/j.mencom.2023.04.004}
}
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Fateev, Sergey Anatol'evich, et al. “Facile method for synthesis of mixed-cation halide perovskites by mild equilibrium conversion via iodine-mediated transport reaction in inert liquid media.” Mendeleev Communications, vol. 33, no. 3, Apr. 2023, pp. 311-313. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.004.

Keywords

hybrid halide perovskites
perovskite photovoltaics.
polyiodides
solid phase equilibria
solid solutions

Abstract

A new facile method for the synthesis of mixed-cation halide R2 = 0.9935 perovskites based on the chemical conversion of solid precursors (organic halides and lead halides) via an iodine-mediated transport reaction in inert liquid media under mild conditions is described. The equilibrium nature of the conversion provides an exact match between the stoichiometry of the resulting perovskite powder and the molar ratio of the precursors. This method can serve as a useful tool for the synthesis of complex perovskite precursors and the investigation of phase equilibria

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