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Mechanochemical tools in the synthesis of organometallic compounds

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Vladimir Andreevich Kozlov 1
Vladimir Andreevich Kozlov
1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
10.1016/j.mencom.2023.04.001
Published 2023-04-13
Communication , Volume 33, Issue 3, 287-301
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Aleksanyan D. V., Kozlov V. A. Mechanochemical tools in the synthesis of organometallic compounds // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 287-301.
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Aleksanyan D. V., Kozlov V. A. Mechanochemical tools in the synthesis of organometallic compounds // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 287-301.
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TY - JOUR
DO - 10.1016/j.mencom.2023.04.001
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.001
TI - Mechanochemical tools in the synthesis of organometallic compounds
T2 - Mendeleev Communications
AU - Aleksanyan, Diana Vladimirovna
AU - Kozlov, Vladimir Andreevich
PY - 2023
DA - 2023/04/13
PB - Mendeleev Communications
SP - 287-301
IS - 3
VL - 33
ER -
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@article{2023_Aleksanyan,
author = {Diana Vladimirovna Aleksanyan and Vladimir Andreevich Kozlov},
title = {Mechanochemical tools in the synthesis of organometallic compounds},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.001},
number = {3},
pages = {287--301},
doi = {10.1016/j.mencom.2023.04.001}
}
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Aleksanyan, Diana Vladimirovna, and Vladimir Andreevich Kozlov. “Mechanochemical tools in the synthesis of organometallic compounds.” Mendeleev Communications, vol. 33, no. 3, Apr. 2023, pp. 287-301. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.04.001.

Keywords

ball milling
green chemistry.
grinding
Mechanochemistry
organometallic compounds
solid-state synthesis
solvent-free reactions

Abstract

In response to rising environmental concerns, chemistry is experiencing a considerable change in both concepts and practices to adopt more efficient and sustainable technologies. One of the alternative technologies that offer many advantages over the conventional solution-based techniques is mechanochemistry which utilizes mechanical energy to induce chemical reactions. Despite the fact that mechanochemistry has reached high significance in the creation of advanced materials, such as alloys, ceramics, electrode materials, and nanocomposites, in the field of small molecule synthesis its potential remains largely untapped. This review highlights the opportunities and prospects of different mechanochemical tools in the synthesis of organometallic compounds, including transition metal complexes with N-heterocyclic carbene, arene, and cyclopentadienyl ligands, monometallacyclic and pincer derivatives, as well as main group metal compounds (e.g., allyl complexes and the Grignard reagents). Many important organometallic transformations such as C-H bond metalation, transmetalation, and oxidative addition can be successfully implemented under mechanochemical conditions in a highly productive and energy-saving manner. Furthermore, the postmodification of metal-containing species upon grinding or milling is shown to be a powerful route to both new discrete metal complexes and different supramolecular architectures (metal-containing organic cages, macrocylces, networks).

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