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The impact of the SnI2 purity on the formation of CsSnI3 perovskite modifications as monitored by 127I Nuclear Quadrupole Resonance

Eleonora Aleksandrovna Kravchenko 1
Eleonora Aleksandrovna Kravchenko
, 
Andrei Andreevich Gippius 2, 3
Andrei Andreevich Gippius
, 
Aleksei Vladimirovich Tkachev 2
Aleksei Vladimirovich Tkachev
, 
Maxim Valeryevich Mastryukov 1
Maxim Valeryevich Mastryukov
, 
2 P.N. Lebedev Physical Institute, Russian Academy of Sciences, Moscow, Russian Federation
3 Department of Physics, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
10.1016/j.mencom.2023.02.043
Published 2023-02-13
Communication , Volume 33, Issue 2, 282-284
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Kravchenko E. A. et al. The impact of the SnI2 purity on the formation of CsSnI3 perovskite modifications as monitored by 127I Nuclear Quadrupole Resonance // Mendeleev Communications. 2023. Vol. 33. No. 2. pp. 282-284.
GOST all authors (up to 50) Copy
Kravchenko E. A., Gippius A. A., Tkachev A. V., Mastryukov M. V., Brekhovskikh M. N. The impact of the SnI2 purity on the formation of CsSnI3 perovskite modifications as monitored by 127I Nuclear Quadrupole Resonance // Mendeleev Communications. 2023. Vol. 33. No. 2. pp. 282-284.
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TY - JOUR
DO - 10.1016/j.mencom.2023.02.043
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.02.043
TI - The impact of the SnI2 purity on the formation of CsSnI3 perovskite modifications as monitored by 127I Nuclear Quadrupole Resonance
T2 - Mendeleev Communications
AU - Kravchenko, Eleonora Aleksandrovna
AU - Gippius, Andrei Andreevich
AU - Tkachev, Aleksei Vladimirovich
AU - Mastryukov, Maxim Valeryevich
AU - Brekhovskikh, Maria Nikolaevna
PY - 2023
DA - 2023/02/13
PB - Mendeleev Communications
SP - 282-284
IS - 2
VL - 33
ER -
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@article{2023_Kravchenko,
author = {Eleonora Aleksandrovna Kravchenko and Andrei Andreevich Gippius and Aleksei Vladimirovich Tkachev and Maxim Valeryevich Mastryukov and Maria Nikolaevna Brekhovskikh},
title = {The impact of the SnI2 purity on the formation of CsSnI3 perovskite modifications as monitored by 127I Nuclear Quadrupole Resonance},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.02.043},
number = {2},
pages = {282--284},
doi = {10.1016/j.mencom.2023.02.043}
}
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Kravchenko, Eleonora Aleksandrovna, et al. “The impact of the SnI2 purity on the formation of CsSnI3 perovskite modifications as monitored by 127I Nuclear Quadrupole Resonance.” Mendeleev Communications, vol. 33, no. 2, Feb. 2023, pp. 282-284. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.02.043.

Keywords

impurities
nuclear quadrupole resonance
perovskites
purification
tin iodide.

Abstract

The relative content of the perovskite phase in two CsSnI3 samples (of 99.900 and 99.999 wt% SnI2 and 99.999 wt% CsI purity) was estimated using 127I NQR. The results showed that both samples contained the non-perovskite orthorhombic phase as an admixture. In the sample of higher purity (99.999 wt%) its content was insignificant - only trace amounts could be observed at 77 K, whereas at room temperature the presence of the non-perovskite phase was not revealed. However, in the sample of 99.900 wt% purity the content of the non-perovskite phase has reached at least a third of the sample amount, which is due to the probable crystallization of the non-perovskite phase on impurities.

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