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Cationic palladium(II)-acetylacetonate complexes bearing pyridinyl imine ligands as catalysts for the hydroamination of phenylacetylene and polymerization of norbornene

Dmitrii Sergeevich Suslov 1
Dmitrii Sergeevich Suslov
, 
Anastasia Vyacheslavovna Suchkova 1
Anastasia Vyacheslavovna Suchkova
, 
Mikhail Valer'evich Bykov 1
Mikhail Valer'evich Bykov
, 
Zorikto Danilovich Abramov 1
Zorikto Danilovich Abramov
, 
Marina Vladimirovna Pakhomova 1
Marina Vladimirovna Pakhomova
, 
Timur Sergeevich Orlov 1
Timur Sergeevich Orlov
, 
Igor Alekseevich Ushakov 2
Igor Alekseevich Ushakov
, 
Tatyana Nikolaevna Borodina 2
Tatyana Nikolaevna Borodina
, 
Vladimir Ilyich Smirnov 2
Vladimir Ilyich Smirnov
1 Research Institute of Oil and Coal Chemical Synthesis, Irkutsk State University, Irkutsk, Russian Federation
10.1016/j.mencom.2023.02.011
Published 2023-02-13
Communication , Volume 33, Issue 2, 184-187
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Suslov D. S. et al. Cationic palladium(II)-acetylacetonate complexes bearing pyridinyl imine ligands as catalysts for the hydroamination of phenylacetylene and polymerization of norbornene // Mendeleev Communications. 2023. Vol. 33. No. 2. pp. 184-187.
GOST all authors (up to 50) Copy
Suslov D. S., Suchkova A. V., Bykov M. V., Abramov Z. D., Pakhomova M. V., Orlov T. S., Ushakov I. A., Borodina T. N., Smirnov V. I. Cationic palladium(II)-acetylacetonate complexes bearing pyridinyl imine ligands as catalysts for the hydroamination of phenylacetylene and polymerization of norbornene // Mendeleev Communications. 2023. Vol. 33. No. 2. pp. 184-187.
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TY - JOUR
DO - 10.1016/j.mencom.2023.02.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.02.011
TI - Cationic palladium(II)-acetylacetonate complexes bearing pyridinyl imine ligands as catalysts for the hydroamination of phenylacetylene and polymerization of norbornene
T2 - Mendeleev Communications
AU - Suslov, Dmitrii Sergeevich
AU - Suchkova, Anastasia Vyacheslavovna
AU - Bykov, Mikhail Valer'evich
AU - Abramov, Zorikto Danilovich
AU - Pakhomova, Marina Vladimirovna
AU - Orlov, Timur Sergeevich
AU - Ushakov, Igor Alekseevich
AU - Borodina, Tatyana Nikolaevna
AU - Smirnov, Vladimir Ilyich
PY - 2023
DA - 2023/02/13
PB - Mendeleev Communications
SP - 184-187
IS - 2
VL - 33
ER -
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@article{2023_Suslov,
author = {Dmitrii Sergeevich Suslov and Anastasia Vyacheslavovna Suchkova and Mikhail Valer'evich Bykov and Zorikto Danilovich Abramov and Marina Vladimirovna Pakhomova and Timur Sergeevich Orlov and Igor Alekseevich Ushakov and Tatyana Nikolaevna Borodina and Vladimir Ilyich Smirnov},
title = {Cationic palladium(II)-acetylacetonate complexes bearing pyridinyl imine ligands as catalysts for the hydroamination of phenylacetylene and polymerization of norbornene},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.02.011},
number = {2},
pages = {184--187},
doi = {10.1016/j.mencom.2023.02.011}
}
MLA
Cite this
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Suslov, Dmitrii Sergeevich, et al. “Cationic palladium(II)-acetylacetonate complexes bearing pyridinyl imine ligands as catalysts for the hydroamination of phenylacetylene and polymerization of norbornene.” Mendeleev Communications, vol. 33, no. 2, Feb. 2023, pp. 184-187. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.02.011.

Keywords

acetylacetonate
hydroamination
imines
norbornene
palladium
phenylacetylene
polymerization.
pyridines

Abstract

Acetylacetonate palladium(II) complexes bearing pyridinyl imine ligands [Pd(acac)(L)]BF4 were synthesized via nitrile displacement in [Pd(acac)(MeCN)2]BF4 by the bidentate ligands L of type 2-C5H4N-CH=N-(CH2)nOMe or 2-C5H4N-CH=N-Ar. The structures of complexes were analyzed by X-ray diffractometry, NMR, and DFT. The complexes catalyze hydroamination of phenylacetylene with aniline to give the Markovnikov imine product as well as polymerization of norbornene.

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