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Crystal structure of tetrakis(triphenylphosphine)palladium(0)

Taisiya Sergeevna Sukhikh 1
Taisiya Sergeevna Sukhikh
, 
Maria Petrovna Davydova 1
Maria Petrovna Davydova
, 
Alexandr Viktorovich Artem’ev 1
Alexandr Viktorovich Artem’ev
1 A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
10.1016/j.mencom.2023.02.007
Published 2023-02-13
Communication , Volume 33, Issue 2, 171-173
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Sukhikh T. S., Davydova M. P., Artem’ev A. V. Crystal structure of tetrakis(triphenylphosphine)palladium(0) // Mendeleev Communications. 2023. Vol. 33. No. 2. pp. 171-173.
GOST all authors (up to 50) Copy
Sukhikh T. S., Davydova M. P., Artem’ev A. V. Crystal structure of tetrakis(triphenylphosphine)palladium(0) // Mendeleev Communications. 2023. Vol. 33. No. 2. pp. 171-173.
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TY - JOUR
DO - 10.1016/j.mencom.2023.02.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.02.007
TI - Crystal structure of tetrakis(triphenylphosphine)palladium(0)
T2 - Mendeleev Communications
AU - Sukhikh, Taisiya Sergeevna
AU - Davydova, Maria Petrovna
AU - Artem’ev, Alexandr Viktorovich
PY - 2023
DA - 2023/02/13
PB - Mendeleev Communications
SP - 171-173
IS - 2
VL - 33
ER -
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@article{2023_Sukhikh,
author = {Taisiya Sergeevna Sukhikh and Maria Petrovna Davydova and Alexandr Viktorovich Artem’ev},
title = {Crystal structure of tetrakis(triphenylphosphine)palladium(0)},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.02.007},
number = {2},
pages = {171--173},
doi = {10.1016/j.mencom.2023.02.007}
}
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Sukhikh, Taisiya Sergeevna, et al. “Crystal structure of tetrakis(triphenylphosphine)palladium(0).” Mendeleev Communications, vol. 33, no. 2, Feb. 2023, pp. 171-173. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.02.007.

Keywords

crystal packing
crystal structure
IR spectra
phase purity control
powder X-ray diffraction analysis.
tetrakis(triphenylphosphine)palladium(0)

Abstract

Crystal structure of widely employed precatalyst [Pd(Ph3P)4] is reported. It crystallizes in P-3 space group [a = 19.0828(8) and c = 26.4423(18) A] with six molecules per unit cell. It is demonstrated that the phase purity of this important compound can now be routinely controlled via powder X-ray diffraction analysis.

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