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Reactivity of digallane toward nitrogen-containing compounds

Tatyana Sergeevna Koptseva 1
Tatyana Sergeevna Koptseva
, 
Natalia L'vovna Bazyakina 1
Natalia L'vovna Bazyakina
, 
Eugeny Vladimirovich Baranov 1
Eugeny Vladimirovich Baranov
, 
Igor Leonidovich Fedushkin 1
Igor Leonidovich Fedushkin
1 G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
10.1016/j.mencom.2023.02.006
Published 2023-02-13
Communication , Volume 33, Issue 2, 167-170
6
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Koptseva T. S. et al. Reactivity of digallane toward nitrogen-containing compounds // Mendeleev Communications. 2023. Vol. 33. No. 2. pp. 167-170.
GOST all authors (up to 50) Copy
Koptseva T. S., Bazyakina N. L., Baranov E. V., Fedushkin I. L. Reactivity of digallane toward nitrogen-containing compounds // Mendeleev Communications. 2023. Vol. 33. No. 2. pp. 167-170.
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TY - JOUR
DO - 10.1016/j.mencom.2023.02.006
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.02.006
TI - Reactivity of digallane toward nitrogen-containing compounds
T2 - Mendeleev Communications
AU - Koptseva, Tatyana Sergeevna
AU - Bazyakina, Natalia L'vovna
AU - Baranov, Eugeny Vladimirovich
AU - Fedushkin, Igor Leonidovich
PY - 2023
DA - 2023/02/13
PB - Mendeleev Communications
SP - 167-170
IS - 2
VL - 33
ER -
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@article{2023_Koptseva,
author = {Tatyana Sergeevna Koptseva and Natalia L'vovna Bazyakina and Eugeny Vladimirovich Baranov and Igor Leonidovich Fedushkin},
title = {Reactivity of digallane toward nitrogen-containing compounds},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.02.006},
number = {2},
pages = {167--170},
doi = {10.1016/j.mencom.2023.02.006}
}
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Koptseva, Tatyana Sergeevna, et al. “Reactivity of digallane toward nitrogen-containing compounds.” Mendeleev Communications, vol. 33, no. 2, Feb. 2023, pp. 167-170. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.02.006.

Keywords

gallium compounds
nitrogen compounds
redox-active ligands
small molecules
X-ray diffraction.

Abstract

The reactions of [LGa-GaL] (L = dpp-bian = 1,2-bis[(2,6-di-isopropylphenyl)imino]acenaphthene) with ammonia and pyrrolidine in toluene lead to the formation of adducts [L(NH3)Ga-Ga(NH3)L], [L(HNC4H8)Ga-GaL] and [L(HNC4H8)Ga-Ga(HNC4H8)L], respectively. In contrast, the reaction between crystalline digallane and an excess of pyrrolidine leads to the formation of compound [LGa(NC4H8)(HNC4H8)]. The complex [LGa(C5H5N)(μ-O)Ga(C5H5N)L] was obtain from reaction of digallane with N2O in the presence of pyridine.

References

.
Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination
Krause L., Herbst-Irmer R., Sheldrick G.M., Stalke D.
Journal of Applied Crystallography, 2015
.
Hydroamination of alkynes with aromatic amines catalyzed by digallane (dpp-bian)Ga—Ga(dpp-bian)
Moskalev M.V., Skatova A.A., Chudakova V.A., Khvoinova N.M., Bazyakina N.L., Morozov A.G., Kazarina O.V., Cherkasov A.V., Abakumov G.A., Fedushkin I.L.
Russian Chemical Bulletin, 2015
.
Redox-Active Ligand-Assisted Two-Electron Oxidative Addition to Gallium(II).
Fedushkin I.L., Dodonov V.A., Skatova A.A., Sokolov V.G., Piskunov A.V., Fukin G.K.
Chemistry - A European Journal, 2018
.
Reversible Addition of Carbon Dioxide to Main Group Metal Complexes at Temperatures about 0 °C
Koptseva T.S., Sokolov V.G., Ketkov S.Y., Rychagova E.A., Cherkasov A.V., Skatova A.A., Fedushkin I.L.
Chemistry - A European Journal, 2021
.
Oxidative Addition of σ Bonds to an Al(I) Center
Chu T., Korobkov I., Nikonov G.I.
Journal of the American Chemical Society, 2014
.
Gallium Hydrides with a Radical-Anionic Ligand
Sokolov V.G., Koptseva T.S., Moskalev M.V., Bazyakina N.L., Piskunov A.V., Cherkasov A.V., Fedushkin I.L.
Inorganic Chemistry, 2017
.
Reactivity of Aluminum Complexes of Redox-Active Ligand toward N-Heterocyclic Carbene and Its Thione
Sokolov V.G., Koptseva T.S., Rumyantcev R.V., Yang X., Zhao Y., Fedushkin I.L.
Organometallics, 2019
.
Reactions of an Aluminum(I) Reagent with 1,2-, 1,3-, and 1,5-Dienes: Dearomatization, Reversibility, and a Pericyclic Mechanism
Bakewell C., Garçon M., Kong R.Y., O’Hare L., White A.J., Crimmin M.R.
Inorganic Chemistry, 2020
.
Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species
Nagata K., Murosaki T., Agou T., Sasamori T., Matsuo T., Tokitoh N.
Angewandte Chemie - International Edition, 2016
.
CO 2 Fixation and Catalytic Reduction by a Neutral Aluminum Double Bond
Weetman C., Bag P., Szilvási T., Jandl C., Inoue S.
Angewandte Chemie - International Edition, 2019
.
Sequential Oxidation and C−H Bond Activation at a Gallium(I) Center
Kassymbek A., Vyboishchikov S.F., Gabidullin B.M., Spasyuk D., Pilkington M., Nikonov G.I.
Angewandte Chemie - International Edition, 2019
.
Element‐Ligand Cooperativity with p‐Block Elements
Greb L., Ebner F., Ginzburg Y., Sigmund L.M.
European Journal of Inorganic Chemistry, 2020
.
The Aluminyl Anion: A New Generation of Aluminium Nucleophile
Hicks J., Vasko P., Goicoechea J.M., Aldridge S.
Angewandte Chemie - International Edition, 2020
.
Aluminum hydrides with radical-anionic and dianionic acenaphthene-1,2-diimine ligands
Sokolov V.G., Koptseva T.S., Moskalev M.V., Piskunov A.V., Samsonov M.A., Fedushkin I.L.
Russian Chemical Bulletin, 2017
.
New Gallium Hydrides with Dianionic Acenaphthene-1,2-Diimine Ligands
Koptseva T.S., Sokolov V.G., Baranov E.V., Fedushkin I.L.
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2020
.
Dialumenes – aryl vs. silyl stabilisation for small molecule activation and catalysis
Weetman C., Porzelt A., Bag P., Hanusch F., Inoue S.
Chemical Science, 2020
.
Organometallo-macrocycle assembled through dialumane-mediated C–H activation of pyridines
Chen W., Liu L., Zhao Y., Xue Y., Xu W., Li N., Wu B., Yang X.
Chemical Communications, 2021
.
Main-group metal complexes of α-diimine ligands: structure, bonding and reactivity
Zhang R., Wang Y., Zhao Y., Redshaw C., Fedushkin I.L., Wu B., Yang X.
Dalton Transactions, 2021
.
Oxidative Addition Reactions of Element-Hydrogen Bonds with Different Polarities to a Gallium(I) Compound
Seifert A., Scheid D., Linti G., Zessin T.
Chemistry - A European Journal, 2009
.
Addition of hydrogen or ammonia to a low-valent group 13 metal species at 25 degrees C and 1 atmosphere.
Zhu Z., Wang X., Peng Y., Lei H., Fettinger J., Rivard E., Power P.
Angewandte Chemie - International Edition, 2009
.
Koptseva T.S., Bazyakina N.L., Rumyantcev R.V., Fedushkin I.L.
Mendeleev Communications, 2022