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Sodium dithionite in the regioselective reduction of the ortho-positioned nitro group in 1-R-2,4-dinitrobenzenes

Michael D Tsymliakov 1
Michael D Tsymliakov
, 
Anita Irekovna Maksutova 1
Anita Irekovna Maksutova
,  , 
Daria Vsevolodovna Zakharova 1
Daria Vsevolodovna Zakharova
,  , 
Victor Aleksandrovich Tafeenko 1
Victor Aleksandrovich Tafeenko
, 
Sergey Evgen'evich Sosonyuk 1
Sergey Evgen'evich Sosonyuk
, 
Natalia Alexandrovna Lozinskaya 1
Natalia Alexandrovna Lozinskaya
1 Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
10.1016/j.mencom.2023.01.038
Published 2022-12-26
Communication , Volume 33, Issue 1, 121-123
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Tsymliakov M. D. et al. Sodium dithionite in the regioselective reduction of the ortho-positioned nitro group in 1-R-2,4-dinitrobenzenes // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 121-123.
GOST all authors (up to 50) Copy
Tsymliakov M. D., Maksutova A. I., Bezsonova E. N., Zakharova D. V., Grishin Y. K., Tafeenko V. A., Sosonyuk S. E., Lozinskaya N. A. Sodium dithionite in the regioselective reduction of the ortho-positioned nitro group in 1-R-2,4-dinitrobenzenes // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 121-123.
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TY - JOUR
DO - 10.1016/j.mencom.2023.01.038
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.038
TI - Sodium dithionite in the regioselective reduction of the ortho-positioned nitro group in 1-R-2,4-dinitrobenzenes
T2 - Mendeleev Communications
AU - Tsymliakov, Michael D
AU - Maksutova, Anita Irekovna
AU - Bezsonova, Elena N
AU - Zakharova, Daria Vsevolodovna
AU - Grishin, Yuri Konstantinovich
AU - Tafeenko, Victor Aleksandrovich
AU - Sosonyuk, Sergey Evgen'evich
AU - Lozinskaya, Natalia Alexandrovna
PY - 2022
DA - 2022/12/26
PB - Mendeleev Communications
SP - 121-123
IS - 1
VL - 33
ER -
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@article{2022_Tsymliakov,
author = {Michael D Tsymliakov and Anita Irekovna Maksutova and Elena N Bezsonova and Daria Vsevolodovna Zakharova and Yuri Konstantinovich Grishin and Victor Aleksandrovich Tafeenko and Sergey Evgen'evich Sosonyuk and Natalia Alexandrovna Lozinskaya},
title = {Sodium dithionite in the regioselective reduction of the ortho-positioned nitro group in 1-R-2,4-dinitrobenzenes},
journal = {Mendeleev Communications},
year = {2022},
volume = {33},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.038},
number = {1},
pages = {121--123},
doi = {10.1016/j.mencom.2023.01.038}
}
MLA
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Tsymliakov, Michael D., et al. “Sodium dithionite in the regioselective reduction of the ortho-positioned nitro group in 1-R-2,4-dinitrobenzenes.” Mendeleev Communications, vol. 33, no. 1, Dec. 2022, pp. 121-123. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.038.
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Keywords

anilines.
dinitroarenes
dithionite
nitro compounds
reduction
regioselectivity

Abstract

1-R-2,4-Dinitrobenzenes are regioselectively reduced with sodium dithionite at near-neutral pH into the product having amino group ortho to the substituent R. Although the yields of products varied from moderate to good, the procedure does not involve the use of transition metals.

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