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Co-Cu-La catalysts for selective CO2 hydrogenation to higher hydrocarbons

Vyacheslav Nikolaevich Borshch 1
Vyacheslav Nikolaevich Borshch
, 
Svetlana Yakovlevna Zhuk 1
Svetlana Yakovlevna Zhuk
, 
Elena Victorovna Pugacheva 1
Elena Victorovna Pugacheva
,  , 
Dmitrii Evgen'evich Andreev 1
Dmitrii Evgen'evich Andreev
, 
Yurii Anatol'evich Agafonov 3
Yurii Anatol'evich Agafonov
, 
Oleg Leonidovich Eliseev 3
Oleg Leonidovich Eliseev
1 A.G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
2 Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation
10.1016/j.mencom.2023.01.017
Published 2022-12-26
Communication , Volume 33, Issue 1, 55-57
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Borshch V. N. et al. Co-Cu-La catalysts for selective CO2 hydrogenation to higher hydrocarbons // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 55-57.
GOST all authors (up to 50) Copy
Borshch V. N., Zhuk S. Y., Pugacheva E. V., Dipheko T. D., Andreev D. E., Agafonov Y. A., Eliseev O. L. Co-Cu-La catalysts for selective CO2 hydrogenation to higher hydrocarbons // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 55-57.
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TY - JOUR
DO - 10.1016/j.mencom.2023.01.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.017
TI - Co-Cu-La catalysts for selective CO2 hydrogenation to higher hydrocarbons
T2 - Mendeleev Communications
AU - Borshch, Vyacheslav Nikolaevich
AU - Zhuk, Svetlana Yakovlevna
AU - Pugacheva, Elena Victorovna
AU - Dipheko, Tshepo Duncan
AU - Andreev, Dmitrii Evgen'evich
AU - Agafonov, Yurii Anatol'evich
AU - Eliseev, Oleg Leonidovich
PY - 2022
DA - 2022/12/26
PB - Mendeleev Communications
SP - 55-57
IS - 1
VL - 33
ER -
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@article{2022_Borshch,
author = {Vyacheslav Nikolaevich Borshch and Svetlana Yakovlevna Zhuk and Elena Victorovna Pugacheva and Tshepo Duncan Dipheko and Dmitrii Evgen'evich Andreev and Yurii Anatol'evich Agafonov and Oleg Leonidovich Eliseev},
title = {Co-Cu-La catalysts for selective CO2 hydrogenation to higher hydrocarbons},
journal = {Mendeleev Communications},
year = {2022},
volume = {33},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.017},
number = {1},
pages = {55--57},
doi = {10.1016/j.mencom.2023.01.017}
}
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Borshch, Vyacheslav Nikolaevich, et al. “Co-Cu-La catalysts for selective CO2 hydrogenation to higher hydrocarbons.” Mendeleev Communications, vol. 33, no. 1, Dec. 2022, pp. 55-57. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.017.
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Keywords

aliphatic hydrocarbons.
carbon capture and utilization
CO2 hydrogenation
cobalt catalyst
copper catalyst
intermetallides

Abstract

Copper and lanthanum promoted cobalt catalysts for CO2 hydrogenation to higher hydrocarbons are described. The catalysts were prepared by the self-propagating high-temperature synthesis followed by alkaline leaching. They are active in CO2 hydrogenation at 200 °C under 10 bar pressure (CO2 : H2 = 1 : 3) with selectivity to C2+ alkanes up to 39%; no alkenes and alcohols are formed under these experimental conditions.

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