Home / Publications / Synthesis of diamantane by skeletal isomerization of pentacyclo[6.6.0.02,6.03,13.010,14]tetradecane induced by ionic liquids

Synthesis of diamantane by skeletal isomerization of pentacyclo[6.6.0.02,6.03,13.010,14]tetradecane induced by ionic liquids

Rishat Ishbirdovich Aminov 1
Rishat Ishbirdovich Aminov
, 
Ravil Ismagilovich Khusnutdinov 1
Ravil Ismagilovich Khusnutdinov
1 Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
10.1016/j.mencom.2023.01.016
Published 2022-12-26
Communication , Volume 33, Issue 1, 53-54
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Aminov R. I., Khusnutdinov R. I. Synthesis of diamantane by skeletal isomerization of pentacyclo[6.6.0.02,6.03,13.010,14]tetradecane induced by ionic liquids // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 53-54.
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Aminov R. I., Khusnutdinov R. I. Synthesis of diamantane by skeletal isomerization of pentacyclo[6.6.0.02,6.03,13.010,14]tetradecane induced by ionic liquids // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 53-54.
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TY - JOUR
DO - 10.1016/j.mencom.2023.01.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.016
TI - Synthesis of diamantane by skeletal isomerization of pentacyclo[6.6.0.02,6.03,13.010,14]tetradecane induced by ionic liquids
T2 - Mendeleev Communications
AU - Aminov, Rishat Ishbirdovich
AU - Khusnutdinov, Ravil Ismagilovich
PY - 2022
DA - 2022/12/26
PB - Mendeleev Communications
SP - 53-54
IS - 1
VL - 33
ER -
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@article{2022_Aminov,
author = {Rishat Ishbirdovich Aminov and Ravil Ismagilovich Khusnutdinov},
title = {Synthesis of diamantane by skeletal isomerization of pentacyclo[6.6.0.02,6.03,13.010,14]tetradecane induced by ionic liquids},
journal = {Mendeleev Communications},
year = {2022},
volume = {33},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.016},
number = {1},
pages = {53--54},
doi = {10.1016/j.mencom.2023.01.016}
}
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Aminov, Rishat Ishbirdovich, and Ravil Ismagilovich Khusnutdinov. “Synthesis of diamantane by skeletal isomerization of pentacyclo[6.6.0.02,6.03,13.010,14]tetradecane induced by ionic liquids.” Mendeleev Communications, vol. 33, no. 1, Dec. 2022, pp. 53-54. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.016.
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Keywords

diamantane
hydrogenation
ionic liquids.
isomerization
norbornadiene dimer

Abstract

Diamantane was synthesized by skeletal isomerization of a 2,6 3,13 10,14 new precursor pentacyclo[6.6.0.02,6.03,13.010,14]tetradecane being the hydrogenated norbornadiene dimer of an unusual structure wholly composed of five-membered rings. The isomerization was induced by ionic liquids based on aluminum, iron, nickel, manganese, zinc, tin, and copper salts, among which aluminate ionic liquids were the most efficient ensuring diamantane yields of up to 85%.

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