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The CH-functionalization of B-substituted organosilicon derivatives of polyhedral carboranes as a way to obtain new materials

, 
Andrey Victorovich Zaitsev 1
Andrey Victorovich Zaitsev
, 
Valentina Antonovna Ol'shevskaya 1
Valentina Antonovna Ol'shevskaya
, 
Aleksandr Sergeevich Peregudov 1
Aleksandr Sergeevich Peregudov
, 
Anton Aleksandrovich Anisimov 1
Anton Aleksandrovich Anisimov
1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
10.1016/j.mencom.2023.01.014
Published 2022-12-26
Communication , Volume 33, Issue 1, 47-49
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Minyaylo E. O. et al. The CH-functionalization of B-substituted organosilicon derivatives of polyhedral carboranes as a way to obtain new materials // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 47-49.
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Minyaylo E. O., Zaitsev A. V., Ol'shevskaya V. A., Peregudov A. S., Anisimov A. A. The CH-functionalization of B-substituted organosilicon derivatives of polyhedral carboranes as a way to obtain new materials // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 47-49.
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TY - JOUR
DO - 10.1016/j.mencom.2023.01.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.014
TI - The CH-functionalization of B-substituted organosilicon derivatives of polyhedral carboranes as a way to obtain new materials
T2 - Mendeleev Communications
AU - Minyaylo, Ekaterina Olegovna
AU - Zaitsev, Andrey Victorovich
AU - Ol'shevskaya, Valentina Antonovna
AU - Peregudov, Aleksandr Sergeevich
AU - Anisimov, Anton Aleksandrovich
PY - 2022
DA - 2022/12/26
PB - Mendeleev Communications
SP - 47-49
IS - 1
VL - 33
ER -
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@article{2022_Minyaylo,
author = {Ekaterina Olegovna Minyaylo and Andrey Victorovich Zaitsev and Valentina Antonovna Ol'shevskaya and Aleksandr Sergeevich Peregudov and Anton Aleksandrovich Anisimov},
title = {The CH-functionalization of B-substituted organosilicon derivatives of polyhedral carboranes as a way to obtain new materials},
journal = {Mendeleev Communications},
year = {2022},
volume = {33},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.014},
number = {1},
pages = {47--49},
doi = {10.1016/j.mencom.2023.01.014}
}
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Minyaylo, Ekaterina Olegovna, et al. “The CH-functionalization of B-substituted organosilicon derivatives of polyhedral carboranes as a way to obtain new materials.” Mendeleev Communications, vol. 33, no. 1, Dec. 2022, pp. 47-49. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.014.
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Keywords

carboranes
carbosilanes
CH-functionalization
core–shell
dendrimers
metallation
organosilicon compounds.

Abstract

The metallation of CH-groups in carboranyl polyhedra with n-butyllithium followed by end-capping with chloro(di-methyl)vinylsilane was explored using a model B-substituted organosilicon derivative obtained previously, the optimal conditions being Et2O, -10 →20 °C, total processing time 125 min. This procedure was applied to prepare a zero-generation polyfunctional B-substituted carborane-carbo-silane dendrimer G0-4 cages.

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