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Halogen-substituted salicylhydroximate copper(II) metallacrowns: from synthesis and structures to novel applications

Marina Aleksandrovna Katkova 1
Marina Aleksandrovna Katkova
, 
Galina Sergeevna Zabrodina 1
Galina Sergeevna Zabrodina
, 
Roman Valeryevich Rumyantcev 1
Roman Valeryevich Rumyantcev
, 
Grigory Yu Zhigulin 1
Grigory Yu Zhigulin
, 
Maria Sergeevna Muravyeva 1, 2
Maria Sergeevna Muravyeva
, 
Margarita Petrovna Shurygina 1, 3
Margarita Petrovna Shurygina
, 
Sergey Arturovich Chesnokov 1
Sergey Arturovich Chesnokov
, 
Sergei Yulievich Ketkov 1
Sergei Yulievich Ketkov
1 G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
2 Privolzhsky Research Medical University, Nizhny Novgorod, Russian Federation
3 Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation
10.1016/j.mencom.2023.01.011
Published 2022-12-26
Communication , Volume 33, Issue 1, 37-40
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Katkova M. A. et al. Halogen-substituted salicylhydroximate copper(II) metallacrowns: from synthesis and structures to novel applications // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 37-40.
GOST all authors (up to 50) Copy
Katkova M. A., Zabrodina G. S., Rumyantcev R. V., Zhigulin G. Yu., Muravyeva M. S., Shurygina M. P., Chesnokov S. A., Ketkov S. Y. Halogen-substituted salicylhydroximate copper(II) metallacrowns: from synthesis and structures to novel applications // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 37-40.
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TY - JOUR
DO - 10.1016/j.mencom.2023.01.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.011
TI - Halogen-substituted salicylhydroximate copper(II) metallacrowns: from synthesis and structures to novel applications
T2 - Mendeleev Communications
AU - Katkova, Marina Aleksandrovna
AU - Zabrodina, Galina Sergeevna
AU - Rumyantcev, Roman Valeryevich
AU - Zhigulin, Grigory Yu
AU - Muravyeva, Maria Sergeevna
AU - Shurygina, Margarita Petrovna
AU - Chesnokov, Sergey Arturovich
AU - Ketkov, Sergei Yulievich
PY - 2022
DA - 2022/12/26
PB - Mendeleev Communications
SP - 37-40
IS - 1
VL - 33
ER -
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@article{2022_Katkova,
author = {Marina Aleksandrovna Katkova and Galina Sergeevna Zabrodina and Roman Valeryevich Rumyantcev and Grigory Yu Zhigulin and Maria Sergeevna Muravyeva and Margarita Petrovna Shurygina and Sergey Arturovich Chesnokov and Sergei Yulievich Ketkov},
title = {Halogen-substituted salicylhydroximate copper(II) metallacrowns: from synthesis and structures to novel applications},
journal = {Mendeleev Communications},
year = {2022},
volume = {33},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.011},
number = {1},
pages = {37--40},
doi = {10.1016/j.mencom.2023.01.011}
}
MLA
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Katkova, Marina Aleksandrovna, et al. “Halogen-substituted salicylhydroximate copper(II) metallacrowns: from synthesis and structures to novel applications.” Mendeleev Communications, vol. 33, no. 1, Dec. 2022, pp. 37-40. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.011.
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Keywords

copper(ii) metallacrowns
DFT calculations
organohalogen compounds
photo- polymerization of dimethacrylate.
salicylhydroxamic acids
X-ray structure

Abstract

New halogen-substituted salicylhydroximate copper(II) metallacrowns were synthesized from Cu(OAc)2 and the corresponding salicylhydroxamic acids. Their molecular structure was determined by single crystal X-ray diffraction. The compounds obtained represent the first members of the metallacrown family that can be used as components of active initiators for the photopolymerization of oligo-carbonate dimethacrylate by visible light.

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