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Synthesis of CF3-substituted isoindolones via rhodium(iii)-catalyzed carbenoid C-H functionalization of aryl hydroxamates

Daria Vladimirovna Vorobyeva 1
Daria Vladimirovna Vorobyeva
,  , 
Anastasiya Georgievna Buyanovskaya 1
Anastasiya Georgievna Buyanovskaya
, 
Sergey Nikolaevich Osipov 1
Sergey Nikolaevich Osipov
1 A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
10.1016/j.mencom.2023.01.010
Published 2022-12-26
Communication , Volume 33, Issue 1, 34-36
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Vorobyeva D. V. et al. Synthesis of CF3-substituted isoindolones via rhodium(iii)-catalyzed carbenoid C-H functionalization of aryl hydroxamates // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 34-36.
GOST all authors (up to 50) Copy
Vorobyeva D. V., Bubnova A. S., Buyanovskaya A. G., Osipov S. N. Synthesis of CF3-substituted isoindolones via rhodium(iii)-catalyzed carbenoid C-H functionalization of aryl hydroxamates // Mendeleev Communications. 2022. Vol. 33. No. 1. pp. 34-36.
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TY - JOUR
DO - 10.1016/j.mencom.2023.01.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.010
TI - Synthesis of CF3-substituted isoindolones via rhodium(iii)-catalyzed carbenoid C-H functionalization of aryl hydroxamates
T2 - Mendeleev Communications
AU - Vorobyeva, Daria Vladimirovna
AU - Bubnova, Alexandra Sergeevna
AU - Buyanovskaya, Anastasiya Georgievna
AU - Osipov, Sergey Nikolaevich
PY - 2022
DA - 2022/12/26
PB - Mendeleev Communications
SP - 34-36
IS - 1
VL - 33
ER -
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@article{2022_Vorobyeva,
author = {Daria Vladimirovna Vorobyeva and Alexandra Sergeevna Bubnova and Anastasiya Georgievna Buyanovskaya and Sergey Nikolaevich Osipov},
title = {Synthesis of CF3-substituted isoindolones via rhodium(iii)-catalyzed carbenoid C-H functionalization of aryl hydroxamates},
journal = {Mendeleev Communications},
year = {2022},
volume = {33},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.010},
number = {1},
pages = {34--36},
doi = {10.1016/j.mencom.2023.01.010}
}
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Vorobyeva, Daria Vladimirovna, et al. “Synthesis of CF3-substituted isoindolones via rhodium(iii)-catalyzed carbenoid C-H functionalization of aryl hydroxamates.” Mendeleev Communications, vol. 33, no. 1, Dec. 2022, pp. 34-36. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2023.01.010.
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Keywords

aryl hydroxamates
C-H activation
diazo compounds
isoindolones
organofluorine compounds.
rhodium(iii) catalysis

Abstract

An efficient method for the selective preparation of trifluoro-methyl-substituted isoindolones has been developed via RhIII catalyzed C-H activation / [4 + 1]-annulation of aryl hydroxamates with functionalized acceptor/acceptor diazo compounds as cross-coupling partners.

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