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Ruthenium-catalyzed methoxycarbonylation of styrene

Oleg Leonidovich Eliseev 1
Oleg Leonidovich Eliseev
, 
Tatyana Nikolaevna Bondarenko 1
Tatyana Nikolaevna Bondarenko
, 
Anastasia B Churikova 2
Anastasia B Churikova
, 
Albert L'vovich Lapidus 1, 2
Albert L'vovich Lapidus
10.1016/j.mencom.2022.11.032
Published 2022-10-21
Communication , Volume 32, Issue 6, 804-806
5
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Eliseev O. L. et al. Ruthenium-catalyzed methoxycarbonylation of styrene // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 804-806.
GOST all authors (up to 50) Copy
Eliseev O. L., Bondarenko T. N., Churikova A. B., Lapidus A. L. Ruthenium-catalyzed methoxycarbonylation of styrene // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 804-806.
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TY - JOUR
DO - 10.1016/j.mencom.2022.11.032
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.032
TI - Ruthenium-catalyzed methoxycarbonylation of styrene
T2 - Mendeleev Communications
AU - Eliseev, Oleg Leonidovich
AU - Bondarenko, Tatyana Nikolaevna
AU - Churikova, Anastasia B
AU - Lapidus, Albert L'vovich
PY - 2022
DA - 2022/10/21
PB - Mendeleev Communications
SP - 804-806
IS - 6
VL - 32
ER -
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@article{2022_Eliseev,
author = {Oleg Leonidovich Eliseev and Tatyana Nikolaevna Bondarenko and Anastasia B Churikova and Albert L'vovich Lapidus},
title = {Ruthenium-catalyzed methoxycarbonylation of styrene},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.032},
number = {6},
pages = {804--806},
doi = {10.1016/j.mencom.2022.11.032}
}
MLA
Cite this
MLA Copy
Eliseev, Oleg Leonidovich, et al. “Ruthenium-catalyzed methoxycarbonylation of styrene.” Mendeleev Communications, vol. 32, no. 6, Oct. 2022, pp. 804-806. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.032.

Keywords

carbon monoxide
carbonylation
methyl phenylpropionate
ruthenium
styrene

Abstract

Methoxycarbonylation of styrene in the presence of homogeneous Ru catalysts is reported for the first time. Available Ru3(CO)12 together with halide source such as [bmim]Br, NaBr or LiCl represents active and easy to handle methoxycarbonylation catalyst. The key advantage of the new catalytic systems over traditional Pd catalysts is their high activity at CO pressure as low as 5 bar.

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