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N-(Chlorodimethylsilyl)methyl anilides: synthesis and structure

Anastasiya Sergeevna Soldatenko 1
Anastasiya Sergeevna Soldatenko
, 
Irina Vladimirovna Sterkhova 1
Irina Vladimirovna Sterkhova
, 
Nataliya Fedorovna Lazareva 1
Nataliya Fedorovna Lazareva
10.1016/j.mencom.2022.11.030
Published 2022-10-21
Communication , Volume 32, Issue 6, 798-800
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Soldatenko A. S., Sterkhova I. V., Lazareva N. F. N-(Chlorodimethylsilyl)methyl anilides: synthesis and structure // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 798-800.
GOST all authors (up to 50) Copy
Soldatenko A. S., Sterkhova I. V., Lazareva N. F. N-(Chlorodimethylsilyl)methyl anilides: synthesis and structure // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 798-800.
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TY - JOUR
DO - 10.1016/j.mencom.2022.11.030
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.030
TI - N-(Chlorodimethylsilyl)methyl anilides: synthesis and structure
T2 - Mendeleev Communications
AU - Soldatenko, Anastasiya Sergeevna
AU - Sterkhova, Irina Vladimirovna
AU - Lazareva, Nataliya Fedorovna
PY - 2022
DA - 2022/10/21
PB - Mendeleev Communications
SP - 798-800
IS - 6
VL - 32
ER -
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@article{2022_Soldatenko,
author = {Anastasiya Sergeevna Soldatenko and Irina Vladimirovna Sterkhova and Nataliya Fedorovna Lazareva},
title = {N-(Chlorodimethylsilyl)methyl anilides: synthesis and structure},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.030},
number = {6},
pages = {798--800},
doi = {10.1016/j.mencom.2022.11.030}
}
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Soldatenko, Anastasiya Sergeevna, et al. “N-(Chlorodimethylsilyl)methyl anilides: synthesis and structure.” Mendeleev Communications, vol. 32, no. 6, Oct. 2022, pp. 798-800. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.030.

Keywords

N-(chlorodimethylsilyl)methyl anilides
N-TMS anilides
chloromethyl(dimethyl)halogenosilanes
NMR
organosilicon compounds
silicon pentacoordinate
X-ray diffraction analysis

Abstract

N-(Chlorodimethylsilyl)methyl anilides of formula RC(O)N(C6H4X)CH2SiMe2Cl (R = Me, Ph; X = H, Me, Cl) were obtained by the reaction of N-TMS-containing anilides with ClCH2Si(Hal)Me2 (Hal = F, Cl). The silicon atom in these compounds is pentacoordinate according to the results of NMR and X-ray diffraction analysis.

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