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Synthesis of alkyl-H-phosphinic acid alkyl esters from red phosphorus and alkyl bromides

Pavel Anatol'evich Volkov 1
Pavel Anatol'evich Volkov
, 
Kseniya Olegovna Khrapova 1
Kseniya Olegovna Khrapova
, 
Anton Alekseevich Telezhkin 1
Anton Alekseevich Telezhkin
, 
Svetlana Filippovna Malysheva 1
Svetlana Filippovna Malysheva
, 
Lyudmila Ivanovna Larina 1
Lyudmila Ivanovna Larina
, 
Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
10.1016/j.mencom.2022.11.028
Published 2022-10-21
Communication , Volume 32, Issue 6, 792-794
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Volkov P. A. et al. Synthesis of alkyl-H-phosphinic acid alkyl esters from red phosphorus and alkyl bromides // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 792-794.
GOST all authors (up to 50) Copy
Volkov P. A., Khrapova K. O., Telezhkin A. A., Malysheva S. F., Larina L. I., Trofimov B. A. Synthesis of alkyl-H-phosphinic acid alkyl esters from red phosphorus and alkyl bromides // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 792-794.
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TY - JOUR
DO - 10.1016/j.mencom.2022.11.028
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.028
TI - Synthesis of alkyl-H-phosphinic acid alkyl esters from red phosphorus and alkyl bromides
T2 - Mendeleev Communications
AU - Volkov, Pavel Anatol'evich
AU - Khrapova, Kseniya Olegovna
AU - Telezhkin, Anton Alekseevich
AU - Malysheva, Svetlana Filippovna
AU - Larina, Lyudmila Ivanovna
AU - Trofimov, Boris Aleksandrovich
PY - 2022
DA - 2022/10/21
PB - Mendeleev Communications
SP - 792-794
IS - 6
VL - 32
ER -
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@article{2022_Volkov,
author = {Pavel Anatol'evich Volkov and Kseniya Olegovna Khrapova and Anton Alekseevich Telezhkin and Svetlana Filippovna Malysheva and Lyudmila Ivanovna Larina and Boris Aleksandrovich Trofimov},
title = {Synthesis of alkyl-H-phosphinic acid alkyl esters from red phosphorus and alkyl bromides},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.028},
number = {6},
pages = {792--794},
doi = {10.1016/j.mencom.2022.11.028}
}
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Volkov, Pavel Anatol'evich, et al. “Synthesis of alkyl-H-phosphinic acid alkyl esters from red phosphorus and alkyl bromides.” Mendeleev Communications, vol. 32, no. 6, Oct. 2022, pp. 792-794. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.028.

Keywords

alkyl bromides
alkyl esters
alkyl-H-phosphinic acids
alkylation
esterification
red phosphorus

Abstract

Alkyl-H-phosphinic acid alkyl esters are synthesized in 65–71% yield via chemoselective reaction of alkyl bromides with available alkyl-H-phosphinic acids (60–65 °C, Et3N). The latter are prepared, in turn, by direct phosphorylation of alkyl bromides with red phosphorus under phase-transfer conditions.

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