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Coordination polymers derived from gallium and zinc metal–metal bonded species

Tatyana Sergeevna Koptseva 1
Tatyana Sergeevna Koptseva
, 
Natalia L'vovna Bazyakina 1
Natalia L'vovna Bazyakina
, 
Roman Valeryevich Rumyantcev 1
Roman Valeryevich Rumyantcev
, 
Igor Leonidovich Fedushkin 1
Igor Leonidovich Fedushkin
10.1016/j.mencom.2022.11.024
Published 2022-10-21
Communication , Volume 32, Issue 6, 780-782
6
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Koptseva T. S. et al. Coordination polymers derived from gallium and zinc metal–metal bonded species // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 780-782.
GOST all authors (up to 50) Copy
Koptseva T. S., Bazyakina N. L., Rumyantcev R. V., Fedushkin I. L. Coordination polymers derived from gallium and zinc metal–metal bonded species // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 780-782.
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TY - JOUR
DO - 10.1016/j.mencom.2022.11.024
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.024
TI - Coordination polymers derived from gallium and zinc metal–metal bonded species
T2 - Mendeleev Communications
AU - Koptseva, Tatyana Sergeevna
AU - Bazyakina, Natalia L'vovna
AU - Rumyantcev, Roman Valeryevich
AU - Fedushkin, Igor Leonidovich
PY - 2022
DA - 2022/10/21
PB - Mendeleev Communications
SP - 780-782
IS - 6
VL - 32
ER -
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@article{2022_Koptseva,
author = {Tatyana Sergeevna Koptseva and Natalia L'vovna Bazyakina and Roman Valeryevich Rumyantcev and Igor Leonidovich Fedushkin},
title = {Coordination polymers derived from gallium and zinc metal–metal bonded species},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.024},
number = {6},
pages = {780--782},
doi = {10.1016/j.mencom.2022.11.024}
}
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Koptseva, Tatyana Sergeevna, et al. “Coordination polymers derived from gallium and zinc metal–metal bonded species.” Mendeleev Communications, vol. 32, no. 6, Oct. 2022, pp. 780-782. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.024.

Keywords

gallium compounds
metal–organic frameworks
redox-active ligands
X-ray diffraction
zinc compounds

Abstract

The reaction of (dpp-bian)Ga–Zn(dpp-bian) (dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) with 1,3-di(4-pyridyl)propane results in 1D coordination polymer [(dpp-bian)Ga–Zn(dpp-bian)(μ2-1,3-Py2(CH2)3)]n with the retained Ga–Zn bond. In contrast, the coordination of 1,3-di(4-pyridyl)propane to Zn atoms in the (dpp-bian)Zn–Zn(dpp-bian) complex induces the cleavage of the Zn–Zn bond which is accompanied by reduction of dpp-bian radical anions to dianions. The reaction product represents 1D coordination polymer [{(dpp-bian)Zn}(μ2-1,3-Py2(CH2)3)]n.

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