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Synthesis of 5-methylidene-2-thio- and 2-selenohydantoins from isothiocyanates or isoselenocyanates and l-serine

Vladimir Konstantinovich Novotortsev 1
Vladimir Konstantinovich Novotortsev
, 
Dmitry Maksimovich Kuandykov 1
Dmitry Maksimovich Kuandykov
,  , 
Nikolai Vasil'evich Zyk 1
Nikolai Vasil'evich Zyk
, 
10.1016/j.mencom.2022.11.020
Published 2022-10-21
Communication , Volume 32, Issue 6, 769-770
6
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Novotortsev V. K. et al. Synthesis of 5-methylidene-2-thio- and 2-selenohydantoins from isothiocyanates or isoselenocyanates and l-serine // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 769-770.
GOST all authors (up to 50) Copy
Novotortsev V. K., Kuandykov D. M., Kukushkin M. E., Zyk N. V., Beloglazkina E. K. Synthesis of 5-methylidene-2-thio- and 2-selenohydantoins from isothiocyanates or isoselenocyanates and l-serine // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 769-770.
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TY - JOUR
DO - 10.1016/j.mencom.2022.11.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.020
TI - Synthesis of 5-methylidene-2-thio- and 2-selenohydantoins from isothiocyanates or isoselenocyanates and l-serine
T2 - Mendeleev Communications
AU - Novotortsev, Vladimir Konstantinovich
AU - Kuandykov, Dmitry Maksimovich
AU - Kukushkin, Maxim Evgenievich
AU - Zyk, Nikolai Vasil'evich
AU - Beloglazkina, Elena Kimovna
PY - 2022
DA - 2022/10/21
PB - Mendeleev Communications
SP - 769-770
IS - 6
VL - 32
ER -
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@article{2022_Novotortsev,
author = {Vladimir Konstantinovich Novotortsev and Dmitry Maksimovich Kuandykov and Maxim Evgenievich Kukushkin and Nikolai Vasil'evich Zyk and Elena Kimovna Beloglazkina},
title = {Synthesis of 5-methylidene-2-thio- and 2-selenohydantoins from isothiocyanates or isoselenocyanates and l-serine},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.020},
number = {6},
pages = {769--770},
doi = {10.1016/j.mencom.2022.11.020}
}
MLA
Cite this
MLA Copy
Novotortsev, Vladimir Konstantinovich, et al. “Synthesis of 5-methylidene-2-thio- and 2-selenohydantoins from isothiocyanates or isoselenocyanates and l-serine.” Mendeleev Communications, vol. 32, no. 6, Oct. 2022, pp. 769-770. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.020.

Keywords

2-selenohydantoins
2-thiohydantoins
dehydration
exocyclic C=C bond
isoselenocyanates
isothiocyanates
l-serine

Abstract

3-Aryl-5-methylidenethiohydantoins and 3-aryl-5-methylidene-selenohydantoins were obtained by one-pot reaction of aryl isothiocyanates or isoselenocyanates with l-serine in NaOH–H2O–Py mixture followed by room temperature HCl-promoted dehydration.

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