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Coordination polymers derived from magnesium and barium complexes of redox-active ligands

Natalia L'vovna Bazyakina 1
Natalia L'vovna Bazyakina
, 
Valentin Mikhailovich Makarov 1
Valentin Mikhailovich Makarov
, 
Mikhail Vladimirovich Moskalev 1
Mikhail Vladimirovich Moskalev
, 
Eugeny Vladimirovich Baranov 1
Eugeny Vladimirovich Baranov
, 
Artem Stepanovich Bogomyakov 2
Artem Stepanovich Bogomyakov
, 
Victor Ivanovich Ovcharenko 2
Victor Ivanovich Ovcharenko
, 
Igor Leonidovich Fedushkin 1
Igor Leonidovich Fedushkin
10.1016/j.mencom.2022.11.017
Published 2022-10-21
Communication , Volume 32, Issue 6, 759-762
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Bazyakina N. L. et al. Coordination polymers derived from magnesium and barium complexes of redox-active ligands // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 759-762.
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Bazyakina N. L., Makarov V. M., Moskalev M. V., Baranov E. V., Bogomyakov A. S., Ovcharenko V. I., Fedushkin I. L. Coordination polymers derived from magnesium and barium complexes of redox-active ligands // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 759-762.
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TY - JOUR
DO - 10.1016/j.mencom.2022.11.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.017
TI - Coordination polymers derived from magnesium and barium complexes of redox-active ligands
T2 - Mendeleev Communications
AU - Bazyakina, Natalia L'vovna
AU - Makarov, Valentin Mikhailovich
AU - Moskalev, Mikhail Vladimirovich
AU - Baranov, Eugeny Vladimirovich
AU - Bogomyakov, Artem Stepanovich
AU - Ovcharenko, Victor Ivanovich
AU - Fedushkin, Igor Leonidovich
PY - 2022
DA - 2022/10/21
PB - Mendeleev Communications
SP - 759-762
IS - 6
VL - 32
ER -
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@article{2022_Bazyakina,
author = {Natalia L'vovna Bazyakina and Valentin Mikhailovich Makarov and Mikhail Vladimirovich Moskalev and Eugeny Vladimirovich Baranov and Artem Stepanovich Bogomyakov and Victor Ivanovich Ovcharenko and Igor Leonidovich Fedushkin},
title = {Coordination polymers derived from magnesium and barium complexes of redox-active ligands},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.017},
number = {6},
pages = {759--762},
doi = {10.1016/j.mencom.2022.11.017}
}
MLA
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Bazyakina, Natalia L'vovna, et al. “Coordination polymers derived from magnesium and barium complexes of redox-active ligands.” Mendeleev Communications, vol. 32, no. 6, Oct. 2022, pp. 759-762. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.017.

Keywords

barium complexes
magnesium complexes
metal–organic coordination polymers
redox-active ligands
X-ray diffraction

Abstract

The reactions of monomeric complexes [(dpp-bian)M(THF)n](M = Mg, n = 3; M = Ba, n = 5; dpp-bian = 1,2-bis[(2,6-di-isopropylphenyl)imino]acenaphthene) with 4,4'-bipyridine (4,4'-bipy) in THF proceed with electron transfer from dpp- bian2– to 4,4'-bipy0 to afford 1D coordination polymers [(dpp-bian)M(4,4'-bipy)(THF)n]m (M = Mg, n = 1; M = Ba, n = 2) that contain simultaneously radical anion ligands dpp-bian– and 4,4'-bipy . Addition of DME to coordination polymer [(dpp-bian)Mg(4,4'-bipy)(THF)n]m results in fragmentation of polymeric chains to give dinuclear magnesium species [{(dpp-bian)Mg(DME)}2(4,4'-bipy)]. Barium analogue [{(dpp-bian)Ba(DME)2}2(4,4'-bipy)] has been prepared by reacting of complex [(dpp-bian)Ba(DME)2.5] with 4,4'-bipy in DME.

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