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Copper- and silver-containing heterometallic iodobismuthates(iii) with 4-(dimethylamino)-1-methylpyridinium cation: structures, thermal stability and optical properties

Irina Aleksandrovna Shentseva 1
Irina Aleksandrovna Shentseva
, 
Andrey Nikolaevich Usoltsev 1
Andrey Nikolaevich Usoltsev
, 
Pavel Aleksandrovich Abramov 1
Pavel Aleksandrovich Abramov
, 
Vladimir Ravilevich Shayapov 1
Vladimir Ravilevich Shayapov
, 
Nikita Alekseevich Korobeynikov 1
Nikita Alekseevich Korobeynikov
, 
Maksim Nail'evich Sokolov 1
Maksim Nail'evich Sokolov
, 
Sergey Alexandrovich Adonin 1
Sergey Alexandrovich Adonin
10.1016/j.mencom.2022.11.015
Published 2022-10-21
Communication , Volume 32, Issue 6, 754-756
11
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Shentseva I. A. et al. Copper- and silver-containing heterometallic iodobismuthates(iii) with 4-(dimethylamino)-1-methylpyridinium cation: structures, thermal stability and optical properties // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 754-756.
GOST all authors (up to 50) Copy
Shentseva I. A., Usoltsev A. N., Abramov P. A., Shayapov V. R., Korobeynikov N. A., Sokolov M. N., Adonin S. A. Copper- and silver-containing heterometallic iodobismuthates(iii) with 4-(dimethylamino)-1-methylpyridinium cation: structures, thermal stability and optical properties // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 754-756.
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TY - JOUR
DO - 10.1016/j.mencom.2022.11.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.015
TI - Copper- and silver-containing heterometallic iodobismuthates(iii) with 4-(dimethylamino)-1-methylpyridinium cation: structures, thermal stability and optical properties
T2 - Mendeleev Communications
AU - Shentseva, Irina Aleksandrovna
AU - Usoltsev, Andrey Nikolaevich
AU - Abramov, Pavel Aleksandrovich
AU - Shayapov, Vladimir Ravilevich
AU - Korobeynikov, Nikita Alekseevich
AU - Sokolov, Maksim Nail'evich
AU - Adonin, Sergey Alexandrovich
PY - 2022
DA - 2022/10/21
PB - Mendeleev Communications
SP - 754-756
IS - 6
VL - 32
ER -
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@article{2022_Shentseva,
author = {Irina Aleksandrovna Shentseva and Andrey Nikolaevich Usoltsev and Pavel Aleksandrovich Abramov and Vladimir Ravilevich Shayapov and Nikita Alekseevich Korobeynikov and Maksim Nail'evich Sokolov and Sergey Alexandrovich Adonin},
title = {Copper- and silver-containing heterometallic iodobismuthates(iii) with 4-(dimethylamino)-1-methylpyridinium cation: structures, thermal stability and optical properties},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.015},
number = {6},
pages = {754--756},
doi = {10.1016/j.mencom.2022.11.015}
}
MLA
Cite this
MLA Copy
Shentseva, Irina Aleksandrovna, et al. “Copper- and silver-containing heterometallic iodobismuthates(iii) with 4-(dimethylamino)-1-methylpyridinium cation: structures, thermal stability and optical properties.” Mendeleev Communications, vol. 32, no. 6, Oct. 2022, pp. 754-756. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.015.

Keywords

Bismuth
copper
halide complexes
semiconductors
silver

Abstract

Reactions of BiI3, copper or silver iodide and 4-(dimethyl-amino)-1-methylpyridinium iodide [(Me-DMAP)I] result in formation of heterometallic complexes (MeDMAP)2{[Bi2Cu2I10]} and (MeDMAP)2{[Bi2Ag2I10]}. Their crystal structures, thermal stability and optical properties have been studied. Optical band gaps calculated from diffuse reflectance spectroscopy data are 1.81 and 2.06 eV for copper- and silver-containing complexes, respectively.

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