Home / Publications / Development and synthesis of novel representatives of polyazido-substituted N-(alkoxymethyl)nitramines

Development and synthesis of novel representatives of polyazido-substituted N-(alkoxymethyl)nitramines

Dmitriy Borisovitsh Vinogradov 1
Dmitriy Borisovitsh Vinogradov
, 
Pavel Valeryevich Bulatov 1
Pavel Valeryevich Bulatov
, 
Evgeny Yuryevich Petrov 1
Evgeny Yuryevich Petrov
, 
Vladimir Alexandrovich Tartakovsky 1
Vladimir Alexandrovich Tartakovsky
10.1016/j.mencom.2022.11.004
Published 2022-10-21
Communication , Volume 32, Issue 6, 720-721
2
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Vinogradov D. B. et al. Development and synthesis of novel representatives of polyazido-substituted N-(alkoxymethyl)nitramines // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 720-721.
GOST all authors (up to 50) Copy
Vinogradov D. B., Bulatov P. V., Petrov E. Y., Tartakovsky V. A. Development and synthesis of novel representatives of polyazido-substituted N-(alkoxymethyl)nitramines // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 720-721.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2022.11.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.004
TI - Development and synthesis of novel representatives of polyazido-substituted N-(alkoxymethyl)nitramines
T2 - Mendeleev Communications
AU - Vinogradov, Dmitriy Borisovitsh
AU - Bulatov, Pavel Valeryevich
AU - Petrov, Evgeny Yuryevich
AU - Tartakovsky, Vladimir Alexandrovich
PY - 2022
DA - 2022/10/21
PB - Mendeleev Communications
SP - 720-721
IS - 6
VL - 32
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2022_Vinogradov,
author = {Dmitriy Borisovitsh Vinogradov and Pavel Valeryevich Bulatov and Evgeny Yuryevich Petrov and Vladimir Alexandrovich Tartakovsky},
title = {Development and synthesis of novel representatives of polyazido-substituted N-(alkoxymethyl)nitramines},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.004},
number = {6},
pages = {720--721},
doi = {10.1016/j.mencom.2022.11.004}
}
MLA
Cite this
MLA Copy
Vinogradov, Dmitriy Borisovitsh, et al. “Development and synthesis of novel representatives of polyazido-substituted N-(alkoxymethyl)nitramines.” Mendeleev Communications, vol. 32, no. 6, Oct. 2022, pp. 720-721. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.004.

Keywords

N-(alkoxymethyl)nitramines
azidation
azides
formation enthalpy
halo alcohols
nitramines
α,ω-dichloro-β-nitrazaalkanes

Abstract

α,ω-Dichloro-β-nitrazaalkanes on treatment with (poly)halo alcohols undergo chemoselective substitution in the activated N-chloromethyl moiety. The thus prepared polyhalo derivatives are converted into the corresponding polyazido compounds which can be the promising energetic plasticizers and monomers.

References

1.
10.1016/j.mencom.2022.11.004_b0005
Chute
J. Can. Res., Sect. B, 1948
2.
10.1016/j.mencom.2022.11.004_b0010
Blomquist
US Patent, 1949
3.
V. M. Zinov’ev, G. V. Kutsenko and A. S. Ermilov, Sovremennye i perspektivnye vysokoenergeticheskie komponenty smesevykh i ballistitnykh tverdykh raketnykh topliv (Modern and Prospective Energetic Components of Composite and Ballistic Solid Propellants), Izd. PGTU, Perm, 2010 (in Russian).
4.
R. L. Simmons, 25th International Annual Conference ICT ‘Thermochemistry of NENA Plasticizers’, Karlsruhe, 1994, 10/1.
5.
Studies on n-Butyl Nitroxyethylnitramine (n-BuNENA): Synthesis, Characterization and Propellant Evaluations
Rao K. ., Sikder A., Kulkarni M., Bhalerao M., Gandhe B.
Propellants, Explosives, Pyrotechnics, 2004
6.
Synthesis of novel energetic compounds. 6
Witucki E.F., Wilson E.R., Flanagan J.E., Frankel M.B.
Journal of Chemical & Engineering Data, 1983
7.
10.1016/j.mencom.2022.11.004_b0035
Sinev
J. Org. Chem., 1982
8.
J. E. Flanagan, E. R. Wilson and M. B. Frankel, US Patent 5013856, 1991.
9.
Nitramine, 11. Mitt. Umsetzungen mit Chlormethyl-alkylnitraminen
Unterhalt B., Leiblein F.
Archiv der Pharmazie, 1978
10.
10.1016/j.mencom.2022.11.004_b0050
Spiridonov
SU Patent, 1976
11.
Vinogradov D.B., Bulatov P.V., Petrov E.Y., Tartakovsky V.A.
Mendeleev Communications, 2021