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Novel (1H-tetrazol-5-yl-NNO-azoxy)furazans and their energetic salts: synthesis, characterization and energetic properties

Nikita E Leonov 1
Nikita E Leonov
, 
Artem Evgenievich Emel’yanov 1, 2
Artem Evgenievich Emel’yanov
,  , 
Aleksandr Mikhailovich Churakov 1
Aleksandr Mikhailovich Churakov
, 
Yurii Andreevich Strelenko 1
Yurii Andreevich Strelenko
, 
Alevtina Nikolaevna Pivkina 3
Alevtina Nikolaevna Pivkina
, 
Ivan Vladimirovich Fedyanin 4, 5
Ivan Vladimirovich Fedyanin
,  , 
Tatiana Sergeevna Kon'kova 3
Tatiana Sergeevna Kon'kova
, 
Yurii Nikolaevich Matyushin 3
Yurii Nikolaevich Matyushin
, 
Vladimir Alexandrovich Tartakovsky 1
Vladimir Alexandrovich Tartakovsky
10.1016/j.mencom.2022.11.002
Published 2022-10-21
Communication , Volume 32, Issue 6, 714-716
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Leonov N. E. et al. Novel (1H-tetrazol-5-yl-NNO-azoxy)furazans and their energetic salts: synthesis, characterization and energetic properties // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 714-716.
GOST all authors (up to 50) Copy
Leonov N. E., Emel’yanov A. E., Klenov M. S., Churakov A. M., Strelenko Y. A., Pivkina A. N., Fedyanin I. V., Lempert D. B., Kon'kova T. S., Matyushin Y. N., Tartakovsky V. A. Novel (1H-tetrazol-5-yl-NNO-azoxy)furazans and their energetic salts: synthesis, characterization and energetic properties // Mendeleev Communications. 2022. Vol. 32. No. 6. pp. 714-716.
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TY - JOUR
DO - 10.1016/j.mencom.2022.11.002
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.002
TI - Novel (1H-tetrazol-5-yl-NNO-azoxy)furazans and their energetic salts: synthesis, characterization and energetic properties
T2 - Mendeleev Communications
AU - Leonov, Nikita E
AU - Emel’yanov, Artem Evgenievich
AU - Klenov, Michael Sergeevich
AU - Churakov, Aleksandr Mikhailovich
AU - Strelenko, Yurii Andreevich
AU - Pivkina, Alevtina Nikolaevna
AU - Fedyanin, Ivan Vladimirovich
AU - Lempert, David Borisovich
AU - Kon'kova, Tatiana Sergeevna
AU - Matyushin, Yurii Nikolaevich
AU - Tartakovsky, Vladimir Alexandrovich
PY - 2022
DA - 2022/10/21
PB - Mendeleev Communications
SP - 714-716
IS - 6
VL - 32
ER -
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@article{2022_Leonov,
author = {Nikita E Leonov and Artem Evgenievich Emel’yanov and Michael Sergeevich Klenov and Aleksandr Mikhailovich Churakov and Yurii Andreevich Strelenko and Alevtina Nikolaevna Pivkina and Ivan Vladimirovich Fedyanin and David Borisovich Lempert and Tatiana Sergeevna Kon'kova and Yurii Nikolaevich Matyushin and Vladimir Alexandrovich Tartakovsky},
title = {Novel (1H-tetrazol-5-yl-NNO-azoxy)furazans and their energetic salts: synthesis, characterization and energetic properties},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.002},
number = {6},
pages = {714--716},
doi = {10.1016/j.mencom.2022.11.002}
}
MLA
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MLA Copy
Leonov, Nikita E., et al. “Novel (1H-tetrazol-5-yl-NNO-azoxy)furazans and their energetic salts: synthesis, characterization and energetic properties.” Mendeleev Communications, vol. 32, no. 6, Oct. 2022, pp. 714-716. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2022.11.002.

Keywords

azoxy compounds
combustion calorimetry
differential scanning calorimetry
enthalpy of formation
furazans
tetrazoles
X-ray diffraction

Abstract

Six novel energetic furazans containing tetrazol-5-yl-NNO-azoxy moiety were synthesized using (cyano-NNO-azoxy)-furazans as starting compounds. The obtained compounds exhibit high enthalpies of formation (531–792 kcal kg–1), acceptable densities (1.70–1.76 g cm–3), good thermal stability (Tonset = 146–199 °C), and, as a result, excellent detonation performance (detonation velocities of 8.61–8.95 km s−1 and detonation pressures of 31.6–36.0 GPa).

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